Preparation of cellulose-tris (phenylcarbamate) coated zirconia and its direct apllication on enantioseparation of glycidyl selenides by high performance liquid chromatography

Huijuan Dun; Shujuan Liu; Yongmin Li; Yongju Wei; Liren Chen

Preparation of cellulose-tris (phenylcarbamate) coated zirconia and its direct apllication on enantioseparation of glycidyl selenides by high performance liquid chromatography

Huijuan Dun, Shujuan Liu, Yongmin Li, Yongju Wei, Liren Chen

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Cellulose-tris (phenylcarbamate) coated zirconia chiral stationary phase (CTPC coated ZrQ₂ CSP) was prepared for high performance liquid chromatography. The chiral stationary phase exhibits good chiral recognition for racemic glycidyl selenides under normal conditions. The relationships between the separation parameters, such as retention factor, enantioselectivity and resolution, and the structures of glycidyl selenides were investigated. The influences of the loading of stationary phase and the solvent polarity of mobile phase on Chromatographic behavior and chiral separation of the analytes were observed. The chiral recognition mechanism of the chiral stationary phase is also discussed.

Original language	English
Pages (from-to)	456-459
Number of pages	4
Journal	Chinese Journal of Chromatography (Se Pu)
Volume	21
Issue number	5
State	Published - 30 Sep 2003
Externally published	Yes

Keywords

Cellulose-tris (phenylcarbamate)
Enantioseparation
Glycidyl selenide
High performance liquid chromatography
Zirconia

Cite this

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title = "Preparation of cellulose-tris (phenylcarbamate) coated zirconia and its direct apllication on enantioseparation of glycidyl selenides by high performance liquid chromatography",

abstract = "Cellulose-tris (phenylcarbamate) coated zirconia chiral stationary phase (CTPC coated ZrQ2 CSP) was prepared for high performance liquid chromatography. The chiral stationary phase exhibits good chiral recognition for racemic glycidyl selenides under normal conditions. The relationships between the separation parameters, such as retention factor, enantioselectivity and resolution, and the structures of glycidyl selenides were investigated. The influences of the loading of stationary phase and the solvent polarity of mobile phase on Chromatographic behavior and chiral separation of the analytes were observed. The chiral recognition mechanism of the chiral stationary phase is also discussed.",

keywords = "Cellulose-tris (phenylcarbamate), Enantioseparation, Glycidyl selenide, High performance liquid chromatography, Zirconia",

author = "Huijuan Dun and Shujuan Liu and Yongmin Li and Yongju Wei and Liren Chen",

year = "2003",

month = sep,

day = "30",

language = "英语",

volume = "21",

pages = "456--459",

journal = "Chinese Journal of Chromatography (Se Pu)",

issn = "1000-8713",

publisher = "Zhongguo Kexueyuan - Chinese Academy of Sciences",

number = "5",

}

Preparation of cellulose-tris (phenylcarbamate) coated zirconia and its direct apllication on enantioseparation of glycidyl selenides by high performance liquid chromatography. / Dun, Huijuan; Liu, Shujuan; Li, Yongmin et al.
In: Chinese Journal of Chromatography (Se Pu), Vol. 21, No. 5, 30.09.2003, p. 456-459.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation of cellulose-tris (phenylcarbamate) coated zirconia and its direct apllication on enantioseparation of glycidyl selenides by high performance liquid chromatography

AU - Dun, Huijuan

AU - Liu, Shujuan

AU - Li, Yongmin

AU - Wei, Yongju

AU - Chen, Liren

PY - 2003/9/30

Y1 - 2003/9/30

N2 - Cellulose-tris (phenylcarbamate) coated zirconia chiral stationary phase (CTPC coated ZrQ2 CSP) was prepared for high performance liquid chromatography. The chiral stationary phase exhibits good chiral recognition for racemic glycidyl selenides under normal conditions. The relationships between the separation parameters, such as retention factor, enantioselectivity and resolution, and the structures of glycidyl selenides were investigated. The influences of the loading of stationary phase and the solvent polarity of mobile phase on Chromatographic behavior and chiral separation of the analytes were observed. The chiral recognition mechanism of the chiral stationary phase is also discussed.

AB - Cellulose-tris (phenylcarbamate) coated zirconia chiral stationary phase (CTPC coated ZrQ2 CSP) was prepared for high performance liquid chromatography. The chiral stationary phase exhibits good chiral recognition for racemic glycidyl selenides under normal conditions. The relationships between the separation parameters, such as retention factor, enantioselectivity and resolution, and the structures of glycidyl selenides were investigated. The influences of the loading of stationary phase and the solvent polarity of mobile phase on Chromatographic behavior and chiral separation of the analytes were observed. The chiral recognition mechanism of the chiral stationary phase is also discussed.

KW - Cellulose-tris (phenylcarbamate)

KW - Enantioseparation

KW - Glycidyl selenide

KW - High performance liquid chromatography

KW - Zirconia

UR - http://www.scopus.com/inward/record.url?scp=54549107877&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:54549107877

SN - 1000-8713

VL - 21

SP - 456

EP - 459

JO - Chinese Journal of Chromatography (Se Pu)

JF - Chinese Journal of Chromatography (Se Pu)

IS - 5

ER -

Preparation of cellulose-tris (phenylcarbamate) coated zirconia and its direct apllication on enantioseparation of glycidyl selenides by high performance liquid chromatography

Abstract

Keywords

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