Preparation and electrorheological characteristics of β-cyclodextrin- epichlorohydrin-starch polymer suspensions

Ziwei Gao, Xiaopeng Zhao

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22 Scopus citations

Abstract

Three environment friendly β-cyclodextrin polymer electrorheological (ER) particles (NS-β-CDP, WSS-β-CDP, and CLS-β-CDP) were synthesized by copolymerization through a mixture of β-cyclodextrin (β-CD) and epichlorohydrin in the absence of starch or in the presence of water-soluble and water-insoluble starch, respectively. The electrorheological properties of suspensions in silicone oil were then investigated under direct current (dc) electric fields. It was found that the yield stress of the typical WSS-β-CDP ER fluid was 6.2 kPa in 4 kV/mm, which is 35% higher than that of NS-β-CDP and similar to that of CLS-β-CDP. In the meantime, it can display a high ER performance even over a range of 65-95°C. The structures of these poly mers were characterized by FT-IR and Raman spectrometry, respectively. The results demonstrated that all of these polymers keep the original structural character of β-CD and the copolymerizations between starch and β-CD indeed occur. Furthermore, it was found that there was some relationship between the characteristic strength of polymers and their dielectric properties. Hence, the improvement of copolymer dielectric properties resulted in the enhancement of ER effects.

Original languageEnglish
Pages (from-to)1681-1686
Number of pages6
JournalJournal of Applied Polymer Science
Volume93
Issue number4
DOIs
StatePublished - 15 Aug 2004

Keywords

  • β-cyclodextrin
  • Copolymerization
  • Electrorheological fluids
  • Host-guest systems
  • Synthesis

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