Polyphenylbenzene as a platform for deep-blue OLEDs: Aggregation enhanced emission and high external quantum efficiency of 3.98%

Xuejun Zhan, Ning Sun, Zhongbin Wu, Jin Tu, Lei Yuan, Xi Tang, Yujun Xie, Qian Peng, Yongqiang Dong, Qianqian Li, Dongge Ma, Zhen Li

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88 Scopus citations

Abstract

Great efforts have been devoted to seek novel approaches for the construction of efficient deep-blue fluorescent materials, one of the most important prerequisites for the commercialization of OLEDs. Here, we report a new way to utilize polyphenylbenzene as a platform to yield a series of efficient deep-blue emitters. Nondoped multilayer electroluminescence (EL) devices using these new luminogens as emitting layers are fabricated. Maximum current efficiency (CE) of 2.0 cd A-1 is achieved and the Commission Internationale de léclairage (CIE) coordinates can stay at (0.15, 0.08), close to the saturated deep-blue (0.14, 0.08). Through rational design of the device structure, blue-violet emission with the CIE coordinates of (0.15, 0.06) can be realized. Furthermore, 10-based doped devices show deep-blue emission with improved CE as high as 4.51 cd A-1, and the external quantum efficiency (EQE) of 3.98%, which are among the best EL performance for deep-blue emission.

Original languageEnglish
Pages (from-to)1847-1854
Number of pages8
JournalChemistry of Materials
Volume27
Issue number5
DOIs
StatePublished - 10 Mar 2015
Externally publishedYes

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