Plasmon-enhanced polymer photovoltaic cells based on large aspect ratio gold nanorods and the related working mechanism

S. F. Chen, F. Cheng, Y. Mei, B. Peng, M. Kong, J. Y. Hao, R. Zhang, Q. H. Xiong, L. H. Wang, W. Huang

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

Two types of Au nanorods (NRs) possessing longitudinal/transverse axes of 55/11 (NR11) and 90/18 nm (NR18) are, respectively, incorporated into the hole extraction layer to improve optical-to-electrical conversion performances in polymer photovoltaic cells. Totally different improvement factors in short-circuit current and power conversion efficiency occur in the NR11- and NR18-doped cells. Optical simulations, electrical analysis, and morphology alteration accompanying with the incorporation of NRs were proceeded to investigate the reason, and analysis demonstrates that a slower damping of field around NRs18 (results in a field and absorption enhancement around the active layer) and one order higher scattering cross section in the NR18-incorporated cell are key factors contributed to the improvement of cell performances.

Original languageEnglish
Article number213903
JournalApplied Physics Letters
Volume104
Issue number21
DOIs
StatePublished - 26 May 2014
Externally publishedYes

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