Palladium-catalyzed carbonylative annulation toward new [1,2,5]thiadiazole-fused heteroacenes for solution-processed field-effect transistors

Shuli Liu; Xin Shi; Yueming Hu; Xinzhen Zhang; Wei Sun; Yuanyuan Qi; Nina Fu; Baomin Zhao; Wei Huang

doi:10.1016/j.tetlet.2016.07.008

Palladium-catalyzed carbonylative annulation toward new [1,2,5]thiadiazole-fused heteroacenes for solution-processed field-effect transistors

Shuli Liu, Xin Shi, Yueming Hu, Xinzhen Zhang, Wei Sun, Yuanyuan Qi, Nina Fu, Baomin Zhao, Wei Huang

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A straightforward synthetic strategy toward [1,2,5]thiadiazole-fused heteroacences via the Pd-catalyzed carbonylative (PdCC) annulation utilizing the building blocks of 5,6-substituted benzo[2,1,3-b]thiadidazole (BT) and 1 atm CO has been successfully developed. Preliminarily, solution-processed Field-effect transistor (FET) devices based on FTC8 exhibited a promising mobility up to 0.177 cm²/(Vs) with a current on/off ratio of nearly 1.2 × 10⁵under an ambient atmosphere. This chemistry opens new perspectives toward high performance heteroacenes.

Original language	English
Pages (from-to)	4452-4455
Number of pages	4
Journal	Tetrahedron Letters
Volume	57
Issue number	40
DOIs	https://doi.org/10.1016/j.tetlet.2016.07.008
State	Published - 2016
Externally published	Yes

Keywords

Heteroacene
Organic field-effect transistor
Palladium-catalyzed carbonylative annulation
Solution-processed
[1,2,5]Thiadiazole

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10.1016/j.tetlet.2016.07.008

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title = "Palladium-catalyzed carbonylative annulation toward new [1,2,5]thiadiazole-fused heteroacenes for solution-processed field-effect transistors",

abstract = "A straightforward synthetic strategy toward [1,2,5]thiadiazole-fused heteroacences via the Pd-catalyzed carbonylative (PdCC) annulation utilizing the building blocks of 5,6-substituted benzo[2,1,3-b]thiadidazole (BT) and 1 atm CO has been successfully developed. Preliminarily, solution-processed Field-effect transistor (FET) devices based on FTC8 exhibited a promising mobility up to 0.177 cm2/(Vs) with a current on/off ratio of nearly 1.2 × 105under an ambient atmosphere. This chemistry opens new perspectives toward high performance heteroacenes.",

keywords = "Heteroacene, Organic field-effect transistor, Palladium-catalyzed carbonylative annulation, Solution-processed, [1,2,5]Thiadiazole",

author = "Shuli Liu and Xin Shi and Yueming Hu and Xinzhen Zhang and Wei Sun and Yuanyuan Qi and Nina Fu and Baomin Zhao and Wei Huang",

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year = "2016",

doi = "10.1016/j.tetlet.2016.07.008",

language = "英语",

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T1 - Palladium-catalyzed carbonylative annulation toward new [1,2,5]thiadiazole-fused heteroacenes for solution-processed field-effect transistors

AU - Liu, Shuli

AU - Shi, Xin

AU - Hu, Yueming

AU - Zhang, Xinzhen

AU - Sun, Wei

AU - Qi, Yuanyuan

AU - Fu, Nina

AU - Zhao, Baomin

AU - Huang, Wei

PY - 2016

Y1 - 2016

N2 - A straightforward synthetic strategy toward [1,2,5]thiadiazole-fused heteroacences via the Pd-catalyzed carbonylative (PdCC) annulation utilizing the building blocks of 5,6-substituted benzo[2,1,3-b]thiadidazole (BT) and 1 atm CO has been successfully developed. Preliminarily, solution-processed Field-effect transistor (FET) devices based on FTC8 exhibited a promising mobility up to 0.177 cm2/(Vs) with a current on/off ratio of nearly 1.2 × 105under an ambient atmosphere. This chemistry opens new perspectives toward high performance heteroacenes.

AB - A straightforward synthetic strategy toward [1,2,5]thiadiazole-fused heteroacences via the Pd-catalyzed carbonylative (PdCC) annulation utilizing the building blocks of 5,6-substituted benzo[2,1,3-b]thiadidazole (BT) and 1 atm CO has been successfully developed. Preliminarily, solution-processed Field-effect transistor (FET) devices based on FTC8 exhibited a promising mobility up to 0.177 cm2/(Vs) with a current on/off ratio of nearly 1.2 × 105under an ambient atmosphere. This chemistry opens new perspectives toward high performance heteroacenes.

KW - Heteroacene

KW - Organic field-effect transistor

KW - Palladium-catalyzed carbonylative annulation

KW - Solution-processed

KW - [1,2,5]Thiadiazole

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U2 - 10.1016/j.tetlet.2016.07.008

DO - 10.1016/j.tetlet.2016.07.008

M3 - 文章

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SN - 0040-4039

VL - 57

SP - 4452

EP - 4455

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 40

ER -

Palladium-catalyzed carbonylative annulation toward new [1,2,5]thiadiazole-fused heteroacenes for solution-processed field-effect transistors

Abstract

Keywords

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