New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

Bing Liu; Cao Fang; Zhi Bing Dong; Jin Shan Li

doi:10.2174/157017807780737327

New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

Bing Liu, Cao Fang, Zhi Bing Dong, Jin Shan Li

Nankai University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).

Original language	English
Pages (from-to)	172-174
Number of pages	3
Journal	Letters in Organic Chemistry
Volume	4
Issue number	3
DOIs	https://doi.org/10.2174/157017807780737327
State	Published - Apr 2007
Externally published	Yes

Keywords

Asymmetric addition
BINOL
Diethylzinc
Schiff base
Titanium

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10.2174/157017807780737327

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title = "New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide",

abstract = "We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).",

keywords = "Asymmetric addition, BINOL, Diethylzinc, Schiff base, Titanium",

author = "Bing Liu and Cao Fang and Dong, {Zhi Bing} and Li, {Jin Shan}",

year = "2007",

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doi = "10.2174/157017807780737327",

language = "英语",

volume = "4",

pages = "172--174",

journal = "Letters in Organic Chemistry",

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AU - Liu, Bing

AU - Fang, Cao

AU - Dong, Zhi Bing

AU - Li, Jin Shan

PY - 2007/4

Y1 - 2007/4

N2 - We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).

AB - We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).

KW - Asymmetric addition

KW - BINOL

KW - Diethylzinc

KW - Schiff base

KW - Titanium

UR - http://www.scopus.com/inward/record.url?scp=35649011457&partnerID=8YFLogxK

U2 - 10.2174/157017807780737327

DO - 10.2174/157017807780737327

M3 - 文章

AN - SCOPUS:35649011457

SN - 1570-1786

VL - 4

SP - 172

EP - 174

JO - Letters in Organic Chemistry

JF - Letters in Organic Chemistry

IS - 3

ER -

New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

Abstract

Keywords

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