Mechanochemical assisted synthesis of titanium silicalite-1

Jun Zhang, Shengru Qiao

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

Titanium Silicalite-1 (TS-1) zeolite was successfully synthesized through a mechanochemical assisted processing. In this method, an amorphous silica-titania precursor was firstly prepared through a mechanochemical treatment. TS-1 was then synthesized by the hydrothermal treatment of the silica-titania precursor with tetrapropylammonium bromide (TPABr) as the template. The results of the XRD, UV-vis, and FT-IR spectrum indicated that the titanium atom was incorporated into the amorphous silica-titania precursor during the grinding, and was also retained in the final TS-1 framework after the hydrothermal treatment. SEM image showed that the TS-1 appeared in a shape of elongated prism. The catalytic performance of TS-1 was examined by phenol hydroxylation with hydrogen peroxide as the oxidant. The results indicated that TS-1 synthesized by this method exhibited a good activity.

Original languageEnglish
Title of host publicationAdvances in Materials and Materials Processing
Pages693-697
Number of pages5
DOIs
StatePublished - 2013
Externally publishedYes
Event2012 3rd International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2012 - Beihai, China
Duration: 22 Dec 201223 Dec 2012

Publication series

NameAdvanced Materials Research
Volume652-654
ISSN (Print)1022-6680

Conference

Conference2012 3rd International Conference on Advances in Materials and Manufacturing Processes, ICAMMP 2012
Country/TerritoryChina
CityBeihai
Period22/12/1223/12/12

Keywords

  • Mechanochemical treatment
  • Silica
  • Titana
  • Titanium silicalite-1
  • TPABr

Fingerprint

Dive into the research topics of 'Mechanochemical assisted synthesis of titanium silicalite-1'. Together they form a unique fingerprint.

Cite this