Large Planar π-Conjugated Porphyrin for Interfacial Engineering in p-i-n Perovskite Solar Cells

Bobo Li; Chaoyue Zheng; Huan Liu; Jie Zhu; Hongmei Zhang; Deqing Gao; Wei Huang

doi:10.1021/acsami.6b10342

Large Planar π-Conjugated Porphyrin for Interfacial Engineering in p-i-n Perovskite Solar Cells

Bobo Li, Chaoyue Zheng, Huan Liu, Jie Zhu, Hongmei Zhang, Deqing Gao, Wei Huang

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

In hybrid organic-inorganic perovskite solar cells (PSCs), interfacial engineering can efficiently improve the photovoltaic performance. In this work, the planar π-conjugated porphyrin, zinc(II) 5,10,15,20-tetrakis[5-(p-acetylthiopentyloxy)phenyl]porphyrin, was developed to modify the interface between poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) and perovskite. The modified devices increased their highest power conversion efficiency (PCE) to 14.05% relative to 11.35% for the reference devices without modification. Such enhancement in efficiency is mainly attributed to the improved open-circuit voltage (V_oc) and fill factor (FF), which benefit from fast hole-extraction and low charge recombination after the employment of well-aligned interlayer.

Original language	English
Pages (from-to)	27438-27443
Number of pages	6
Journal	ACS Applied Materials and Interfaces
Volume	8
Issue number	41
DOIs	https://doi.org/10.1021/acsami.6b10342
State	Published - 19 Oct 2016
Externally published	Yes

Keywords

charge recombination
hole extraction
interfacial modification
perovskite solar cell
porphyrin

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acsami.6b10342

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title = "Large Planar π-Conjugated Porphyrin for Interfacial Engineering in p-i-n Perovskite Solar Cells",

abstract = "In hybrid organic-inorganic perovskite solar cells (PSCs), interfacial engineering can efficiently improve the photovoltaic performance. In this work, the planar π-conjugated porphyrin, zinc(II) 5,10,15,20-tetrakis[5-(p-acetylthiopentyloxy)phenyl]porphyrin, was developed to modify the interface between poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) and perovskite. The modified devices increased their highest power conversion efficiency (PCE) to 14.05% relative to 11.35% for the reference devices without modification. Such enhancement in efficiency is mainly attributed to the improved open-circuit voltage (Voc) and fill factor (FF), which benefit from fast hole-extraction and low charge recombination after the employment of well-aligned interlayer.",

keywords = "charge recombination, hole extraction, interfacial modification, perovskite solar cell, porphyrin",

author = "Bobo Li and Chaoyue Zheng and Huan Liu and Jie Zhu and Hongmei Zhang and Deqing Gao and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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day = "19",

doi = "10.1021/acsami.6b10342",

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T1 - Large Planar π-Conjugated Porphyrin for Interfacial Engineering in p-i-n Perovskite Solar Cells

AU - Li, Bobo

AU - Zheng, Chaoyue

AU - Liu, Huan

AU - Zhu, Jie

AU - Zhang, Hongmei

AU - Gao, Deqing

AU - Huang, Wei

PY - 2016/10/19

Y1 - 2016/10/19

N2 - In hybrid organic-inorganic perovskite solar cells (PSCs), interfacial engineering can efficiently improve the photovoltaic performance. In this work, the planar π-conjugated porphyrin, zinc(II) 5,10,15,20-tetrakis[5-(p-acetylthiopentyloxy)phenyl]porphyrin, was developed to modify the interface between poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) and perovskite. The modified devices increased their highest power conversion efficiency (PCE) to 14.05% relative to 11.35% for the reference devices without modification. Such enhancement in efficiency is mainly attributed to the improved open-circuit voltage (Voc) and fill factor (FF), which benefit from fast hole-extraction and low charge recombination after the employment of well-aligned interlayer.

AB - In hybrid organic-inorganic perovskite solar cells (PSCs), interfacial engineering can efficiently improve the photovoltaic performance. In this work, the planar π-conjugated porphyrin, zinc(II) 5,10,15,20-tetrakis[5-(p-acetylthiopentyloxy)phenyl]porphyrin, was developed to modify the interface between poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) and perovskite. The modified devices increased their highest power conversion efficiency (PCE) to 14.05% relative to 11.35% for the reference devices without modification. Such enhancement in efficiency is mainly attributed to the improved open-circuit voltage (Voc) and fill factor (FF), which benefit from fast hole-extraction and low charge recombination after the employment of well-aligned interlayer.

KW - charge recombination

KW - hole extraction

KW - interfacial modification

KW - perovskite solar cell

KW - porphyrin

UR - http://www.scopus.com/inward/record.url?scp=84992170475&partnerID=8YFLogxK

U2 - 10.1021/acsami.6b10342

DO - 10.1021/acsami.6b10342

M3 - 文章

AN - SCOPUS:84992170475

SN - 1944-8244

VL - 8

SP - 27438

EP - 27443

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 41

ER -

Large Planar π-Conjugated Porphyrin for Interfacial Engineering in p-i-n Perovskite Solar Cells

Abstract

Keywords

UN SDGs

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