Ionothermal Synthesis of Open-Framework Metal Phosphates Using a Multifunctional Ionic Liquid

Kangcai Wang; Ting Li; Hongmei Zeng; Guohong Zou; Qinghua Zhang; Zhien Lin

doi:10.1021/acs.inorgchem.8b01509

Ionothermal Synthesis of Open-Framework Metal Phosphates Using a Multifunctional Ionic Liquid

Kangcai Wang, Ting Li, Hongmei Zeng, Guohong Zou, Qinghua Zhang, Zhien Lin

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Two crystalline metal phosphates (metal = Be and Al) were prepared under ionothermal conditions using a multifunctional ionic liquid as a solvent, a structure-directing agent, and a phosphorus source. The beryllium phosphate has a three-dimensional structure with intersecting 24-membered ring (24 MR) channels. The aluminum phosphate has a two-dimensional structure containing 8 MR windows. It displays exceptional hydrothermal stability and shows a high proton conductivity on the order of 10^-3 S cm^-1 at 25 °C under high humidity conditions.

Original language	English
Pages (from-to)	8726-8729
Number of pages	4
Journal	Inorganic Chemistry
Volume	57
Issue number	15
DOIs	https://doi.org/10.1021/acs.inorgchem.8b01509
State	Published - 6 Aug 2018
Externally published	Yes

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title = "Ionothermal Synthesis of Open-Framework Metal Phosphates Using a Multifunctional Ionic Liquid",

abstract = "Two crystalline metal phosphates (metal = Be and Al) were prepared under ionothermal conditions using a multifunctional ionic liquid as a solvent, a structure-directing agent, and a phosphorus source. The beryllium phosphate has a three-dimensional structure with intersecting 24-membered ring (24 MR) channels. The aluminum phosphate has a two-dimensional structure containing 8 MR windows. It displays exceptional hydrothermal stability and shows a high proton conductivity on the order of 10-3 S cm-1 at 25 °C under high humidity conditions.",

author = "Kangcai Wang and Ting Li and Hongmei Zeng and Guohong Zou and Qinghua Zhang and Zhien Lin",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

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doi = "10.1021/acs.inorgchem.8b01509",

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T1 - Ionothermal Synthesis of Open-Framework Metal Phosphates Using a Multifunctional Ionic Liquid

AU - Wang, Kangcai

AU - Li, Ting

AU - Zeng, Hongmei

AU - Zou, Guohong

AU - Zhang, Qinghua

AU - Lin, Zhien

PY - 2018/8/6

Y1 - 2018/8/6

N2 - Two crystalline metal phosphates (metal = Be and Al) were prepared under ionothermal conditions using a multifunctional ionic liquid as a solvent, a structure-directing agent, and a phosphorus source. The beryllium phosphate has a three-dimensional structure with intersecting 24-membered ring (24 MR) channels. The aluminum phosphate has a two-dimensional structure containing 8 MR windows. It displays exceptional hydrothermal stability and shows a high proton conductivity on the order of 10-3 S cm-1 at 25 °C under high humidity conditions.

AB - Two crystalline metal phosphates (metal = Be and Al) were prepared under ionothermal conditions using a multifunctional ionic liquid as a solvent, a structure-directing agent, and a phosphorus source. The beryllium phosphate has a three-dimensional structure with intersecting 24-membered ring (24 MR) channels. The aluminum phosphate has a two-dimensional structure containing 8 MR windows. It displays exceptional hydrothermal stability and shows a high proton conductivity on the order of 10-3 S cm-1 at 25 °C under high humidity conditions.

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U2 - 10.1021/acs.inorgchem.8b01509

DO - 10.1021/acs.inorgchem.8b01509

M3 - 文章

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AN - SCOPUS:85051144677

SN - 0020-1669

VL - 57

SP - 8726

EP - 8729

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Ionothermal Synthesis of Open-Framework Metal Phosphates Using a Multifunctional Ionic Liquid

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