Investigation on influence of Ta on microstructure evolution of directionally solidified Ni-based superalloys

Peng Peng, Li Lu, Zijie Liu, Yuanli Xu, Xudong Zhang, Zhikun Ma, Hong Zhang, Min Guo, Lin Liu

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The microstructure evolution in directionally solidified Ni-based superalloys DZ411 with different Tantalum (Ta) compositions (2.72, 3.10, and 4.00 wt%) was investigated to develop Ta-containing hot corrosion superalloys. It is found that the addition of Ta promote the element segregation in the interdendritic region, thus, leading to the increase in volume fraction of MC carbides and eutectics, while the morphology of them are not obviously changed. In addition, both the volume fraction of regions increases with increasing Ta composition, which is attributed to the reason that Ta is the main forming element of γ' phase. Besides, the previous controversy on the dependence of both the primary and secondary dendrite arm spacing on Ta composition was solved. The increase of dendrite arm spacing with increasing Ta composition can be attributed to increasing solidification range of these superalloys through both JMatPro and Different Scanning Calorimetry (DSC) analysis. Furthermore, the atomic arrangement of γ and γ' phases in alloys was characterized by spherical aberration corrected transmission electron microscopy. Both the saturation of refractory elements in γ matrix and the lattice constant of γ matrix was found to increase with increasing Ta composition, leading to the increase of lattice mismatch of γ/γ' phase and more regular shape of γ' phase which has also been confirmed by JMatPro analysis.

Original languageEnglish
Article number167009
JournalJournal of Alloys and Compounds
Volume927
DOIs
StatePublished - 15 Dec 2022

Keywords

  • Directional solidification
  • Lattice mismatch
  • Ni-based superalloys
  • Tantalum

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