Abstract
Mesoporous MnO 2/polyaniline composite (MP-I) has been synthesized using an interfacial synthesis technique. The results of X-ray diffraction and Fourier transform infrared spectroscopy indicate the amorphous structure of MP-I. The morphology of MP-I observed by scanning electron microscopy and transmission electron microscopy is composed of hierarchical hollow submicron spheres. The N 2 adsorption/desorption test reveals MP-I has higher surface area (124 m 2 g -1) and more uniform pore-size distribution than the composite (MP-C) prepared by chemical co-precipitation. The electrochemical measurements show that as electrode materials the mesoporous MP-I composite electrode yields larger specific capacitance (262 F g -1) with better rate capability and higher capacitance retention (93% of its initial capacitance after 800 cycles). The unique microstructure of MP-I and the coexistence of conducting polyaniline with MnO 2 are found to be responsible for the superior electrochemical properties.
Original language | English |
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Pages (from-to) | 236-243 |
Number of pages | 8 |
Journal | Journal of Power Sources |
Volume | 204 |
DOIs | |
State | Published - 15 Apr 2012 |
Externally published | Yes |
Keywords
- Composite
- Interfacial synthesis
- Manganese oxide
- Polyaniline
- Supercapacitor