Interfacial synthesis of mesoporous MnO 2/polyaniline hollow spheres and their application in electrochemical capacitors

Jian Gan Wang, Ying Yang, Zheng Hong Huang, Feiyu Kang

Research output: Contribution to journalArticlepeer-review

172 Scopus citations

Abstract

Mesoporous MnO 2/polyaniline composite (MP-I) has been synthesized using an interfacial synthesis technique. The results of X-ray diffraction and Fourier transform infrared spectroscopy indicate the amorphous structure of MP-I. The morphology of MP-I observed by scanning electron microscopy and transmission electron microscopy is composed of hierarchical hollow submicron spheres. The N 2 adsorption/desorption test reveals MP-I has higher surface area (124 m 2 g -1) and more uniform pore-size distribution than the composite (MP-C) prepared by chemical co-precipitation. The electrochemical measurements show that as electrode materials the mesoporous MP-I composite electrode yields larger specific capacitance (262 F g -1) with better rate capability and higher capacitance retention (93% of its initial capacitance after 800 cycles). The unique microstructure of MP-I and the coexistence of conducting polyaniline with MnO 2 are found to be responsible for the superior electrochemical properties.

Original languageEnglish
Pages (from-to)236-243
Number of pages8
JournalJournal of Power Sources
Volume204
DOIs
StatePublished - 15 Apr 2012
Externally publishedYes

Keywords

  • Composite
  • Interfacial synthesis
  • Manganese oxide
  • Polyaniline
  • Supercapacitor

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