Interfacial engineering of self-assembled monolayer modified semi-roll-to-roll planar heterojunction perovskite solar cells on flexible substrates

Zhuowei Gu, Lijian Zuo, Thue T. Larsen-Olsen, Tao Ye, Gang Wu, Frederik C. Krebs, Hongzheng Chen

Research output: Contribution to journalArticlepeer-review

155 Scopus citations

Abstract

The morphologies of the perovskite (e.g. CH3NH3PbI3) layer are demonstrated to be critically important for highly efficient perovskite solar cells. This work applies 3-aminopropanoic acid as a self-assembled monolayer (C3-SAM) on a poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole transport layer (HTL) to modify the crystallinity and coverage of the CH3NH3PbI3-xClx film, resulting in a much smoother perovskite surface morphology together with a PCE increase from 9.7% to 11.6%. Since all fabrication steps of these inverted structure devices are carried out under low temperature conditions (processing temperature < 120 °C), it is possible to employ this method on flexible polymer substrates using roll-coating for the layer deposition. The roll-coated perovskite film on C3-SAM modified PEDOT:PSS presents a similar trend of improvement and results in enhanced PCE from 3.7% to 5.1%. The successful application of the facile HTL modification indicates a common strategy for SAM material design and selection for efficiency enhancement in perovskite photovoltaic devices.

Original languageEnglish
Pages (from-to)24254-24260
Number of pages7
JournalJournal of Materials Chemistry A
Volume3
Issue number48
DOIs
StatePublished - 2015
Externally publishedYes

Fingerprint

Dive into the research topics of 'Interfacial engineering of self-assembled monolayer modified semi-roll-to-roll planar heterojunction perovskite solar cells on flexible substrates'. Together they form a unique fingerprint.

Cite this