Highly dispersed CuO nanoparticle on ZIF-4 framework as anode material for LIBs

Jiali Chai; Ke Wang; Qingmeng Li; Jiakai Du; Lei Jiang; Ning Han; Wei Zhang; Bohejin Tang; Yichuan Rui

doi:10.1016/j.jallcom.2022.165316

Highly dispersed CuO nanoparticle on ZIF-4 framework as anode material for LIBs

Jiali Chai, Ke Wang, Qingmeng Li, Jiakai Du, Lei Jiang, Ning Han, Wei Zhang, Bohejin Tang, Yichuan Rui

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A novel prepared ZIF-4@CuO is proposed as lithium-ion battery (LIB) anode material in this work. ZIF-4-CuCl₂ is prepared by the hydrogen extraction reaction in which CuCl₂ replaced the hydrogen sites on the imidazole-based N-heterocyclic carbene of ZIF-4 for under basic conditions. ZIF-4@CuO was prepared by decomposition of ZIF-4-CuCl₂ precursor. The formed CuO was isolated and highly dispersed by the ZIF-4 frame. The combination of porous structure by ZIF and highly dispersed CuO nanoparticles strongly promotes the reaction kinetics of the electrode. The reversible specific capacity of ZIF-4@CuO anode material is 425 mA h g^-1 at 1000 mA g^-1 after 300 cycles, exhibits excellent electrochemical performance in LIBs. The preparation of highly dispersed nanoparticles explores a novel strategy for the anodes design of LIBs with superior performance.

Original language	English
Article number	165316
Journal	Journal of Alloys and Compounds
Volume	914
DOIs	https://doi.org/10.1016/j.jallcom.2022.165316
State	Published - 5 Sep 2022
Externally published	Yes

Keywords

Highly dispersed CuO nanoparticles
Hydrogen extraction reaction
Lithium-ion battery
ZIF-4-CuCl
ZIF-4@CuO

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jallcom.2022.165316

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title = "Highly dispersed CuO nanoparticle on ZIF-4 framework as anode material for LIBs",

abstract = "A novel prepared ZIF-4@CuO is proposed as lithium-ion battery (LIB) anode material in this work. ZIF-4-CuCl2 is prepared by the hydrogen extraction reaction in which CuCl2 replaced the hydrogen sites on the imidazole-based N-heterocyclic carbene of ZIF-4 for under basic conditions. ZIF-4@CuO was prepared by decomposition of ZIF-4-CuCl2 precursor. The formed CuO was isolated and highly dispersed by the ZIF-4 frame. The combination of porous structure by ZIF and highly dispersed CuO nanoparticles strongly promotes the reaction kinetics of the electrode. The reversible specific capacity of ZIF-4@CuO anode material is 425 mA h g-1 at 1000 mA g-1 after 300 cycles, exhibits excellent electrochemical performance in LIBs. The preparation of highly dispersed nanoparticles explores a novel strategy for the anodes design of LIBs with superior performance.",

keywords = "Highly dispersed CuO nanoparticles, Hydrogen extraction reaction, Lithium-ion battery, ZIF-4-CuCl, ZIF-4@CuO",

author = "Jiali Chai and Ke Wang and Qingmeng Li and Jiakai Du and Lei Jiang and Ning Han and Wei Zhang and Bohejin Tang and Yichuan Rui",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2022",

month = sep,

day = "5",

doi = "10.1016/j.jallcom.2022.165316",

language = "英语",

volume = "914",

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TY - JOUR

T1 - Highly dispersed CuO nanoparticle on ZIF-4 framework as anode material for LIBs

AU - Chai, Jiali

AU - Wang, Ke

AU - Li, Qingmeng

AU - Du, Jiakai

AU - Jiang, Lei

AU - Han, Ning

AU - Zhang, Wei

AU - Tang, Bohejin

AU - Rui, Yichuan

PY - 2022/9/5

Y1 - 2022/9/5

N2 - A novel prepared ZIF-4@CuO is proposed as lithium-ion battery (LIB) anode material in this work. ZIF-4-CuCl2 is prepared by the hydrogen extraction reaction in which CuCl2 replaced the hydrogen sites on the imidazole-based N-heterocyclic carbene of ZIF-4 for under basic conditions. ZIF-4@CuO was prepared by decomposition of ZIF-4-CuCl2 precursor. The formed CuO was isolated and highly dispersed by the ZIF-4 frame. The combination of porous structure by ZIF and highly dispersed CuO nanoparticles strongly promotes the reaction kinetics of the electrode. The reversible specific capacity of ZIF-4@CuO anode material is 425 mA h g-1 at 1000 mA g-1 after 300 cycles, exhibits excellent electrochemical performance in LIBs. The preparation of highly dispersed nanoparticles explores a novel strategy for the anodes design of LIBs with superior performance.

AB - A novel prepared ZIF-4@CuO is proposed as lithium-ion battery (LIB) anode material in this work. ZIF-4-CuCl2 is prepared by the hydrogen extraction reaction in which CuCl2 replaced the hydrogen sites on the imidazole-based N-heterocyclic carbene of ZIF-4 for under basic conditions. ZIF-4@CuO was prepared by decomposition of ZIF-4-CuCl2 precursor. The formed CuO was isolated and highly dispersed by the ZIF-4 frame. The combination of porous structure by ZIF and highly dispersed CuO nanoparticles strongly promotes the reaction kinetics of the electrode. The reversible specific capacity of ZIF-4@CuO anode material is 425 mA h g-1 at 1000 mA g-1 after 300 cycles, exhibits excellent electrochemical performance in LIBs. The preparation of highly dispersed nanoparticles explores a novel strategy for the anodes design of LIBs with superior performance.

KW - Highly dispersed CuO nanoparticles

KW - Hydrogen extraction reaction

KW - Lithium-ion battery

KW - ZIF-4-CuCl

KW - ZIF-4@CuO

UR - http://www.scopus.com/inward/record.url?scp=85130406353&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2022.165316

DO - 10.1016/j.jallcom.2022.165316

M3 - 文章

AN - SCOPUS:85130406353

SN - 0925-8388

VL - 914

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

M1 - 165316

ER -

Highly dispersed CuO nanoparticle on ZIF-4 framework as anode material for LIBs

Abstract

Keywords

UN SDGs

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