High-loading and thermally stable Pt1/MgAl1.2Fe0.8O4 single-atom catalysts for high-temperature applications

Kaipeng Liu; Yan Tang; Zhiyang Yu; Binghui Ge; Guoqing Ren; Yujing Ren; Yang Su; Jingcai Zhang; Xiucheng Sun; Zhiqiang Chen; Xiaoyan Liu; Botao Qiao; Wei Zhen Li; Aiqin Wang; Jun Li

doi:10.1007/s40843-020-1267-2

High-loading and thermally stable Pt₁/MgAl_1.2Fe_0.8O₄ single-atom catalysts for high-temperature applications

Kaipeng Liu, Yan Tang, Zhiyang Yu, Binghui Ge, Guoqing Ren, Yujing Ren, Yang Su, Jingcai Zhang, Xiucheng Sun, Zhiqiang Chen, Xiaoyan Liu, Botao Qiao, Wei Zhen Li, Aiqin Wang, Jun Li

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Single-atom catalysts (SACs) have attracted extensive attention in the field of heterogeneous catalysis. However, the fabrication of SACs with high loading and high-temperature stability remains a grand challenge, especially on oxide supports. In this work, we have demonstrated that through strong covalent metal-support interaction, high-loading and thermally stable single-atom Pt catalysts can be readily prepared by using Fe modified spinel as support. Better catalytic performance in N₂O decomposition reaction is obtained on such SACs than their nanocatalyst counterpart and low-surface-area Fe₂O₃ supported Pt SACs. This work provides a strategy for the fabrication of high-loading and thermally stable SACs for applications at high temperatures.

Translated title of the contribution	高载量高温热稳定的Pt₁/MgAl_1.2Fe_0.8O₄单原子催化剂
Original language	English
Pages (from-to)	949-958
Number of pages	10
Journal	Science China Materials
Volume	63
Issue number	6
DOIs	https://doi.org/10.1007/s40843-020-1267-2
State	Published - 1 Jun 2020
Externally published	Yes

Keywords

high loading
NO decomposition
single-atom catalyst
strong covalent metal-support interaction
thermal stability

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10.1007/s40843-020-1267-2

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title = "High-loading and thermally stable Pt1/MgAl1.2Fe0.8O4 single-atom catalysts for high-temperature applications",

abstract = "Single-atom catalysts (SACs) have attracted extensive attention in the field of heterogeneous catalysis. However, the fabrication of SACs with high loading and high-temperature stability remains a grand challenge, especially on oxide supports. In this work, we have demonstrated that through strong covalent metal-support interaction, high-loading and thermally stable single-atom Pt catalysts can be readily prepared by using Fe modified spinel as support. Better catalytic performance in N2O decomposition reaction is obtained on such SACs than their nanocatalyst counterpart and low-surface-area Fe2O3 supported Pt SACs. This work provides a strategy for the fabrication of high-loading and thermally stable SACs for applications at high temperatures.",

keywords = "high loading, NO decomposition, single-atom catalyst, strong covalent metal-support interaction, thermal stability",

author = "Kaipeng Liu and Yan Tang and Zhiyang Yu and Binghui Ge and Guoqing Ren and Yujing Ren and Yang Su and Jingcai Zhang and Xiucheng Sun and Zhiqiang Chen and Xiaoyan Liu and Botao Qiao and Li, {Wei Zhen} and Aiqin Wang and Jun Li",

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month = jun,

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doi = "10.1007/s40843-020-1267-2",

language = "英语",

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T1 - High-loading and thermally stable Pt1/MgAl1.2Fe0.8O4 single-atom catalysts for high-temperature applications

AU - Liu, Kaipeng

AU - Tang, Yan

AU - Yu, Zhiyang

AU - Ge, Binghui

AU - Ren, Guoqing

AU - Ren, Yujing

AU - Su, Yang

AU - Zhang, Jingcai

AU - Sun, Xiucheng

AU - Chen, Zhiqiang

AU - Liu, Xiaoyan

AU - Qiao, Botao

AU - Li, Wei Zhen

AU - Wang, Aiqin

AU - Li, Jun

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Single-atom catalysts (SACs) have attracted extensive attention in the field of heterogeneous catalysis. However, the fabrication of SACs with high loading and high-temperature stability remains a grand challenge, especially on oxide supports. In this work, we have demonstrated that through strong covalent metal-support interaction, high-loading and thermally stable single-atom Pt catalysts can be readily prepared by using Fe modified spinel as support. Better catalytic performance in N2O decomposition reaction is obtained on such SACs than their nanocatalyst counterpart and low-surface-area Fe2O3 supported Pt SACs. This work provides a strategy for the fabrication of high-loading and thermally stable SACs for applications at high temperatures.

AB - Single-atom catalysts (SACs) have attracted extensive attention in the field of heterogeneous catalysis. However, the fabrication of SACs with high loading and high-temperature stability remains a grand challenge, especially on oxide supports. In this work, we have demonstrated that through strong covalent metal-support interaction, high-loading and thermally stable single-atom Pt catalysts can be readily prepared by using Fe modified spinel as support. Better catalytic performance in N2O decomposition reaction is obtained on such SACs than their nanocatalyst counterpart and low-surface-area Fe2O3 supported Pt SACs. This work provides a strategy for the fabrication of high-loading and thermally stable SACs for applications at high temperatures.

KW - high loading

KW - NO decomposition

KW - single-atom catalyst

KW - strong covalent metal-support interaction

KW - thermal stability

UR - http://www.scopus.com/inward/record.url?scp=85080901450&partnerID=8YFLogxK

U2 - 10.1007/s40843-020-1267-2

DO - 10.1007/s40843-020-1267-2

M3 - 文章

AN - SCOPUS:85080901450

SN - 2095-8226

VL - 63

SP - 949

EP - 958

JO - Science China Materials

JF - Science China Materials

IS - 6

ER -

High-loading and thermally stable Pt₁/MgAl_1.2Fe_0.8O₄ single-atom catalysts for high-temperature applications

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Keywords

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