TY - JOUR
T1 - Granular Nanosheets Made of Interconnected NiTe2-CoTe2Nanoparticles on Carbon Fibers for High-Performance Hybrid Supercapacitors
AU - Shi, Chao
AU - Yang, Qingjun
AU - Chen, Shengyu
AU - Xue, Yanping
AU - Hao, Yue
AU - Yan, Yongsheng
N1 - Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.
PY - 2022/3/28
Y1 - 2022/3/28
N2 - Recently, metal tellurides have been widely used as functional materials in energy storage, environment, or catalysis. However, designing synergistic bimetallic tellurides with excellent electrochemical performance remains a huge challenge, especially in high-performance supercapacitors. Herein, high-capacity nickel-cobalt telluride nanosheets were synthesized on carbon fibers (CF@CoTe2-NiTe2). First, using Co-MOF nanosheet arrays as template, nickel-cobalt layered double hydroxide nanosheets were prepared by a simple Ni ion etching. Then, the CF@CoTe2-NiTe2was fabricated based on the as-obtained NiCo-LDH nanoarrays in tellurium vapor. Significantly, the CoTe2-NiTe2nanosheets are made up of many interconnected CoTe2and NiTe2nanoparticles, enhancing the effective contact with the electrolyte solution during the oxidation reaction. The as-prepared CF@CoTe2-NiTe2exhibits a high electrochemical capacitance of 261.4 mAh g-1at 1.0 A g-1and an outstanding capacitance retention of 70% when the current density reached 20 A g-1. Remarkably, the hybrid supercapacitor assembled by CF@CoTe2-NiTe2and CF@Fe2O3presents 41 Wh kg-1at 750 W kg-1, with a high capacitance retention (87.6% after 5000 cycles). Therefore, bimetallic tellurides may be used as more functional materials for applying to energy storage.
AB - Recently, metal tellurides have been widely used as functional materials in energy storage, environment, or catalysis. However, designing synergistic bimetallic tellurides with excellent electrochemical performance remains a huge challenge, especially in high-performance supercapacitors. Herein, high-capacity nickel-cobalt telluride nanosheets were synthesized on carbon fibers (CF@CoTe2-NiTe2). First, using Co-MOF nanosheet arrays as template, nickel-cobalt layered double hydroxide nanosheets were prepared by a simple Ni ion etching. Then, the CF@CoTe2-NiTe2was fabricated based on the as-obtained NiCo-LDH nanoarrays in tellurium vapor. Significantly, the CoTe2-NiTe2nanosheets are made up of many interconnected CoTe2and NiTe2nanoparticles, enhancing the effective contact with the electrolyte solution during the oxidation reaction. The as-prepared CF@CoTe2-NiTe2exhibits a high electrochemical capacitance of 261.4 mAh g-1at 1.0 A g-1and an outstanding capacitance retention of 70% when the current density reached 20 A g-1. Remarkably, the hybrid supercapacitor assembled by CF@CoTe2-NiTe2and CF@Fe2O3presents 41 Wh kg-1at 750 W kg-1, with a high capacitance retention (87.6% after 5000 cycles). Therefore, bimetallic tellurides may be used as more functional materials for applying to energy storage.
KW - Co-MOF
KW - CoTe-NiTeinterconnected nanoparticles
KW - NiCo-LDH nanosheets
KW - supercapacitor
KW - ultrahigh capacitance
UR - http://www.scopus.com/inward/record.url?scp=85125301246&partnerID=8YFLogxK
U2 - 10.1021/acsaem.1c03437
DO - 10.1021/acsaem.1c03437
M3 - 文章
AN - SCOPUS:85125301246
SN - 2574-0962
VL - 5
SP - 2817
EP - 2825
JO - ACS Applied Energy Materials
JF - ACS Applied Energy Materials
IS - 3
ER -