Abstract
A series of fluorene-based grid molecules (so-called Grid fluorenes) have been synthesized by means of shape-supported cyclization, starting from H-shaped precursors via the alternative Friedel-Crafts reactions of fluorenols and Suzuki cross-coupling reactions with key cyclization yields up to 26%. Fluorenol approaches and nanogrids open a door to soluble one-, two-, or three-dimensional nanoporous polymers as next-generation polymer mechano-semiconductors facing a new era of consciousness.
Original language | English |
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Pages (from-to) | 1748-1751 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 16 |
Issue number | 6 |
DOIs | |
State | Published - 21 Mar 2014 |
Externally published | Yes |