Fluorescence turn-on probe for Hg2+ based on schiff base derivative containing sulfur

Jie Na Weng; Qun Bo Mei; Yuan Zhi Jiang; Bin Zhang; Juan Song; Qi Dan Ling; Qu Li Fan; Wei Huang

Fluorescence turn-on probe for Hg²⁺ based on schiff base derivative containing sulfur

Jie Na Weng, Qun Bo Mei, Yuan Zhi Jiang, Bin Zhang, Juan Song, Qi Dan Ling, Qu Li Fan, Wei Huang

Research output: Contribution to journal › Article › peer-review

Abstract

A novel fluorescence turn-on probe based on a new schiff base derivative CzSB containing sulfur atoms is designed and prepared for detection of Hg²⁺ in the presence of other competing metal ions in acetonitrile. The addition of Hg²⁺ significantly enhances the fluorescence emission intensity of CzSB. The turn-on behavior of the probe is ascribed to the metal ion-induced conformational changes from the weak N-phenyl carbazole monomer emission to intensive excimer emission. The photophysical properties and Job plot of CzSB toward Hg²⁺ confirme a 1:2 (CzSB-Hg²⁺) binding mode and a possible binding mechanism.

Original language	English
Pages (from-to)	94-99
Number of pages	6
Journal	Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)
Volume	34
Issue number	2
State	Published - Apr 2014
Externally published	Yes

Keywords

Chemosensor
Schiff base
Turn-on fluorescence probe

Cite this

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title = "Fluorescence turn-on probe for Hg2+ based on schiff base derivative containing sulfur",

abstract = "A novel fluorescence turn-on probe based on a new schiff base derivative CzSB containing sulfur atoms is designed and prepared for detection of Hg2+ in the presence of other competing metal ions in acetonitrile. The addition of Hg2+ significantly enhances the fluorescence emission intensity of CzSB. The turn-on behavior of the probe is ascribed to the metal ion-induced conformational changes from the weak N-phenyl carbazole monomer emission to intensive excimer emission. The photophysical properties and Job plot of CzSB toward Hg2+ confirme a 1:2 (CzSB-Hg2+) binding mode and a possible binding mechanism.",

keywords = "Chemosensor, Schiff base, Turn-on fluorescence probe",

author = "Weng, {Jie Na} and Mei, {Qun Bo} and Jiang, {Yuan Zhi} and Bin Zhang and Juan Song and Ling, {Qi Dan} and Fan, {Qu Li} and Wei Huang",

year = "2014",

month = apr,

language = "英语",

volume = "34",

pages = "94--99",

journal = "Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)",

issn = "1673-5439",

publisher = "Journal of Nanjing Institute of Posts and Telecommunications",

number = "2",

}

Fluorescence turn-on probe for Hg²⁺ based on schiff base derivative containing sulfur. / Weng, Jie Na; Mei, Qun Bo; Jiang, Yuan Zhi et al.
In: Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science), Vol. 34, No. 2, 04.2014, p. 94-99.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Fluorescence turn-on probe for Hg2+ based on schiff base derivative containing sulfur

AU - Weng, Jie Na

AU - Mei, Qun Bo

AU - Jiang, Yuan Zhi

AU - Zhang, Bin

AU - Song, Juan

AU - Ling, Qi Dan

AU - Fan, Qu Li

AU - Huang, Wei

PY - 2014/4

Y1 - 2014/4

N2 - A novel fluorescence turn-on probe based on a new schiff base derivative CzSB containing sulfur atoms is designed and prepared for detection of Hg2+ in the presence of other competing metal ions in acetonitrile. The addition of Hg2+ significantly enhances the fluorescence emission intensity of CzSB. The turn-on behavior of the probe is ascribed to the metal ion-induced conformational changes from the weak N-phenyl carbazole monomer emission to intensive excimer emission. The photophysical properties and Job plot of CzSB toward Hg2+ confirme a 1:2 (CzSB-Hg2+) binding mode and a possible binding mechanism.

AB - A novel fluorescence turn-on probe based on a new schiff base derivative CzSB containing sulfur atoms is designed and prepared for detection of Hg2+ in the presence of other competing metal ions in acetonitrile. The addition of Hg2+ significantly enhances the fluorescence emission intensity of CzSB. The turn-on behavior of the probe is ascribed to the metal ion-induced conformational changes from the weak N-phenyl carbazole monomer emission to intensive excimer emission. The photophysical properties and Job plot of CzSB toward Hg2+ confirme a 1:2 (CzSB-Hg2+) binding mode and a possible binding mechanism.

KW - Chemosensor

KW - Schiff base

KW - Turn-on fluorescence probe

UR - http://www.scopus.com/inward/record.url?scp=84901236094&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:84901236094

SN - 1673-5439

VL - 34

SP - 94

EP - 99

JO - Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)

JF - Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)

IS - 2

ER -

Fluorescence turn-on probe for Hg²⁺ based on schiff base derivative containing sulfur

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Keywords

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