Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Jingyu Shi; Kangcai Wang; Jing Li; Hongmei Zeng; Qinghua Zhang; Zhien Lin

doi:10.1039/c7dt04125j

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Jingyu Shi, Kangcai Wang, Jing Li, Hongmei Zeng, Qinghua Zhang, Zhien Lin

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Two new metal phosphates, namely, Zn(HPO₄)(dl-C₃H₇NO₂) (SCU-4) and In(HPO₄)(H₂PO₄)(dl-C₃H₇NO₂) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

Original language	English
Pages (from-to)	654-658
Number of pages	5
Journal	Dalton Transactions
Volume	47
Issue number	3
DOIs	https://doi.org/10.1039/c7dt04125j
State	Published - 2018
Externally published	Yes

Access to Document

10.1039/c7dt04125j

Cite this

@article{4b36c62c23db4e798a669c9be68c4bce,

title = "Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system",

abstract = "Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.",

author = "Jingyu Shi and Kangcai Wang and Jing Li and Hongmei Zeng and Qinghua Zhang and Zhien Lin",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c7dt04125j",

language = "英语",

volume = "47",

pages = "654--658",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

AU - Shi, Jingyu

AU - Wang, Kangcai

AU - Li, Jing

AU - Zeng, Hongmei

AU - Zhang, Qinghua

AU - Lin, Zhien

PY - 2018

Y1 - 2018

N2 - Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

AB - Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

UR - http://www.scopus.com/inward/record.url?scp=85046105233&partnerID=8YFLogxK

U2 - 10.1039/c7dt04125j

DO - 10.1039/c7dt04125j

M3 - 文章

C2 - 29226288

AN - SCOPUS:85046105233

SN - 1477-9226

VL - 47

SP - 654

EP - 658

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Abstract

Access to Document

Other files and links

Fingerprint

Cite this