Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one

Shu Guang Wen; Wei Min Liu; Yong Min Liang

doi:10.1021/jo800556e

Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one

Shu Guang Wen, Wei Min Liu, Yong Min Liang

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

(Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.

Original language	English
Pages (from-to)	4342-4344
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	73
Issue number	11
DOIs	https://doi.org/10.1021/jo800556e
State	Published - 6 Jun 2008
Externally published	Yes

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title = "Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one",

abstract = "(Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.",

author = "Wen, {Shu Guang} and Liu, {Wei Min} and Liang, {Yong Min}",

year = "2008",

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doi = "10.1021/jo800556e",

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journal = "Journal of Organic Chemistry",

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AU - Wen, Shu Guang

AU - Liu, Wei Min

AU - Liang, Yong Min

PY - 2008/6/6

Y1 - 2008/6/6

N2 - (Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.

AB - (Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.

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M3 - 文章

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one

Abstract

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