Efficient adsorptive removal of dibenzothiophene by graphene oxide-based surface molecularly imprinted polymer

Feifei Duan; Chaoqiu Chen; Guizhen Wang; Yongzhen Yang; Xuguang Liu; Yong Qin

doi:10.1039/c3ra45354e

Efficient adsorptive removal of dibenzothiophene by graphene oxide-based surface molecularly imprinted polymer

Feifei Duan, Chaoqiu Chen, Guizhen Wang, Yongzhen Yang, Xuguang Liu, Yong Qin

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Molecularly imprinted polymers on GO nanosheets (MIPs/GO) for desulfurization are synthesized using dibenzothiophene (DBT) as template, methacrylic acid (MAA) as monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker. The formation of this hybrid material is verified by Fourier transform infrared spectroscopy, thermal gravimetric and atomic force microscopy analysis. The adsorption results show that the prepared MIPs/GO exhibit excellent adsorption capacity (up to 181.9 mg g^-1 at 298 K) and fast mass transfer and binding kinetics for DBT. The kinetics and isotherm data can be well described by the pseudo-first-order kinetic model and the Freundlich isotherm, respectively. Competitive adsorption experiments demonstrate that MIPs/GO show higher affinity toward target molecule DBT than toward structural analogue benzothiophene.

Original language	English
Pages (from-to)	1469-1475
Number of pages	7
Journal	RSC Advances
Volume	4
Issue number	3
DOIs	https://doi.org/10.1039/c3ra45354e
State	Published - 2014
Externally published	Yes

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title = "Efficient adsorptive removal of dibenzothiophene by graphene oxide-based surface molecularly imprinted polymer",

abstract = "Molecularly imprinted polymers on GO nanosheets (MIPs/GO) for desulfurization are synthesized using dibenzothiophene (DBT) as template, methacrylic acid (MAA) as monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker. The formation of this hybrid material is verified by Fourier transform infrared spectroscopy, thermal gravimetric and atomic force microscopy analysis. The adsorption results show that the prepared MIPs/GO exhibit excellent adsorption capacity (up to 181.9 mg g-1 at 298 K) and fast mass transfer and binding kinetics for DBT. The kinetics and isotherm data can be well described by the pseudo-first-order kinetic model and the Freundlich isotherm, respectively. Competitive adsorption experiments demonstrate that MIPs/GO show higher affinity toward target molecule DBT than toward structural analogue benzothiophene.",

author = "Feifei Duan and Chaoqiu Chen and Guizhen Wang and Yongzhen Yang and Xuguang Liu and Yong Qin",

year = "2014",

doi = "10.1039/c3ra45354e",

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pages = "1469--1475",

journal = "RSC Advances",

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T1 - Efficient adsorptive removal of dibenzothiophene by graphene oxide-based surface molecularly imprinted polymer

AU - Duan, Feifei

AU - Chen, Chaoqiu

AU - Wang, Guizhen

AU - Yang, Yongzhen

AU - Liu, Xuguang

AU - Qin, Yong

PY - 2014

Y1 - 2014

N2 - Molecularly imprinted polymers on GO nanosheets (MIPs/GO) for desulfurization are synthesized using dibenzothiophene (DBT) as template, methacrylic acid (MAA) as monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker. The formation of this hybrid material is verified by Fourier transform infrared spectroscopy, thermal gravimetric and atomic force microscopy analysis. The adsorption results show that the prepared MIPs/GO exhibit excellent adsorption capacity (up to 181.9 mg g-1 at 298 K) and fast mass transfer and binding kinetics for DBT. The kinetics and isotherm data can be well described by the pseudo-first-order kinetic model and the Freundlich isotherm, respectively. Competitive adsorption experiments demonstrate that MIPs/GO show higher affinity toward target molecule DBT than toward structural analogue benzothiophene.

AB - Molecularly imprinted polymers on GO nanosheets (MIPs/GO) for desulfurization are synthesized using dibenzothiophene (DBT) as template, methacrylic acid (MAA) as monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker. The formation of this hybrid material is verified by Fourier transform infrared spectroscopy, thermal gravimetric and atomic force microscopy analysis. The adsorption results show that the prepared MIPs/GO exhibit excellent adsorption capacity (up to 181.9 mg g-1 at 298 K) and fast mass transfer and binding kinetics for DBT. The kinetics and isotherm data can be well described by the pseudo-first-order kinetic model and the Freundlich isotherm, respectively. Competitive adsorption experiments demonstrate that MIPs/GO show higher affinity toward target molecule DBT than toward structural analogue benzothiophene.

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U2 - 10.1039/c3ra45354e

DO - 10.1039/c3ra45354e

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Efficient adsorptive removal of dibenzothiophene by graphene oxide-based surface molecularly imprinted polymer

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