Effects of DNP on thermolysis and combustion characteristics of CMDB propellant

Xiao Fei Qi; Qi Long Yan; Han Wang; La Ying Zhang

Effects of DNP on thermolysis and combustion characteristics of CMDB propellant

Xiao Fei Qi, Qi Long Yan, Han Wang, La Ying Zhang

Xi'an Modern Chemistry Research Institute

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The effects of 1, 4-dinitropiperazine (DNP) on the combustion characteristics and thermolysis of CMDB propellants were studied by differential scanning calorimetry (DSC) and burning rate test. Results show that the thermolysis of RDX in propellants are affected obviously by DNP, and the burning rate and pressure index of CMDB propellants decrease with the increasing of DNP content. These phenomena become more evident when the pressure is 12-18 MPa. In addition, when the DNP content increases to 20% (DN3), there is an extra thermal decomposition peak of DNP which is separated from the main exothermic peak, and there is a lower exothermic peak beside it with the pressure increasing to 9 MPa.

Original language	English
Pages (from-to)	451-454
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	17
Issue number	4
State	Published - Aug 2009
Externally published	Yes

Keywords

1, 4-dinitropiperazine (DNP)
Combustion characteristic
Modified double base propellant (CMDB)
PDSC
Physical chemistry

Cite this

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title = "Effects of DNP on thermolysis and combustion characteristics of CMDB propellant",

abstract = "The effects of 1, 4-dinitropiperazine (DNP) on the combustion characteristics and thermolysis of CMDB propellants were studied by differential scanning calorimetry (DSC) and burning rate test. Results show that the thermolysis of RDX in propellants are affected obviously by DNP, and the burning rate and pressure index of CMDB propellants decrease with the increasing of DNP content. These phenomena become more evident when the pressure is 12-18 MPa. In addition, when the DNP content increases to 20% (DN3), there is an extra thermal decomposition peak of DNP which is separated from the main exothermic peak, and there is a lower exothermic peak beside it with the pressure increasing to 9 MPa.",

keywords = "1, 4-dinitropiperazine (DNP), Combustion characteristic, Modified double base propellant (CMDB), PDSC, Physical chemistry",

author = "Qi, {Xiao Fei} and Yan, {Qi Long} and Han Wang and Zhang, {La Ying}",

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T1 - Effects of DNP on thermolysis and combustion characteristics of CMDB propellant

AU - Qi, Xiao Fei

AU - Yan, Qi Long

AU - Wang, Han

AU - Zhang, La Ying

PY - 2009/8

Y1 - 2009/8

N2 - The effects of 1, 4-dinitropiperazine (DNP) on the combustion characteristics and thermolysis of CMDB propellants were studied by differential scanning calorimetry (DSC) and burning rate test. Results show that the thermolysis of RDX in propellants are affected obviously by DNP, and the burning rate and pressure index of CMDB propellants decrease with the increasing of DNP content. These phenomena become more evident when the pressure is 12-18 MPa. In addition, when the DNP content increases to 20% (DN3), there is an extra thermal decomposition peak of DNP which is separated from the main exothermic peak, and there is a lower exothermic peak beside it with the pressure increasing to 9 MPa.

AB - The effects of 1, 4-dinitropiperazine (DNP) on the combustion characteristics and thermolysis of CMDB propellants were studied by differential scanning calorimetry (DSC) and burning rate test. Results show that the thermolysis of RDX in propellants are affected obviously by DNP, and the burning rate and pressure index of CMDB propellants decrease with the increasing of DNP content. These phenomena become more evident when the pressure is 12-18 MPa. In addition, when the DNP content increases to 20% (DN3), there is an extra thermal decomposition peak of DNP which is separated from the main exothermic peak, and there is a lower exothermic peak beside it with the pressure increasing to 9 MPa.

KW - 1, 4-dinitropiperazine (DNP)

KW - Combustion characteristic

KW - Modified double base propellant (CMDB)

KW - PDSC

KW - Physical chemistry

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SN - 1006-9941

VL - 17

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EP - 454

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 4

ER -

Effects of DNP on thermolysis and combustion characteristics of CMDB propellant

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