TY - JOUR
T1 - Dual-Functional Mesoporous Films Templated by Cellulose Nanocrystals for the Selective Adsorption of Lithium and Rubidium
AU - Zheng, Xudong
AU - Wang, Yuanyuan
AU - Qiu, Fengxian
AU - Li, Zhongyu
AU - Yan, Yongsheng
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/3/14
Y1 - 2019/3/14
N2 - Lithium resources are an emerging issue due to lithium ion batteries. Rubidium is also widely used in the field of energy and medicine, so it makes sense for the dual adsorption of lithium and rubidium at the same time. Cellulose nanocrystalline (CNC) is used as a biotemplate to synthesis mesoporous films, and hydrogen manganese oxide (HMO) is immobilized on a mesoporous film. Then Rb(I) ionic imprinted layer is grafted onto the surface of a mesoporous film to obtain a dual-functional mesoporous film. Dual-functional mesoporous films possess high selective adsorptions of Li(I) and Rb(I) and show excellent adsorption kinetic properties of Li(I) and Rb(I). The adsorption capacities of Li(I) and Rb(I) are 6.30 and 6.21 mg g -1 under optimum conditions, respectively. HMO ion sieves and ionic imprinting make films demonstrating a high selectivity in the adsorption of Li(I) and Rb(I), enhancing their potential for industrial applications.
AB - Lithium resources are an emerging issue due to lithium ion batteries. Rubidium is also widely used in the field of energy and medicine, so it makes sense for the dual adsorption of lithium and rubidium at the same time. Cellulose nanocrystalline (CNC) is used as a biotemplate to synthesis mesoporous films, and hydrogen manganese oxide (HMO) is immobilized on a mesoporous film. Then Rb(I) ionic imprinted layer is grafted onto the surface of a mesoporous film to obtain a dual-functional mesoporous film. Dual-functional mesoporous films possess high selective adsorptions of Li(I) and Rb(I) and show excellent adsorption kinetic properties of Li(I) and Rb(I). The adsorption capacities of Li(I) and Rb(I) are 6.30 and 6.21 mg g -1 under optimum conditions, respectively. HMO ion sieves and ionic imprinting make films demonstrating a high selectivity in the adsorption of Li(I) and Rb(I), enhancing their potential for industrial applications.
UR - http://www.scopus.com/inward/record.url?scp=85062105682&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.8b00731
DO - 10.1021/acs.jced.8b00731
M3 - 文章
AN - SCOPUS:85062105682
SN - 0021-9568
VL - 64
SP - 926
EP - 933
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 3
ER -
