Diarylfluorene-based shape-persistent organic nanomolecular frameworks via iterative Friedel-Crafts protocol toward multicomponent organic semiconductors

Guang Wei Zhang; Long Wang; Ling Hai Xie; Xiao Ya Hou; Zheng Dong Liu; Wei Huang

doi:10.1155/2013/368202

Diarylfluorene-based shape-persistent organic nanomolecular frameworks via iterative Friedel-Crafts protocol toward multicomponent organic semiconductors

Guang Wei Zhang, Long Wang, Ling Hai Xie, Xiao Ya Hou, Zheng Dong Liu, Wei Huang

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

We describe bottom-up fluorenol approach to create soluble covalent organic nanomolecular architectures (ONAs) as potential multicomponent organic semiconductors (MOSs). BPyFBFFA as a typical model of ONAs and MOSs exhibits a persistent chair-shaped geometric structure that consists of hole-transporting triphenylamine (TPA), high-efficiency terfluorene, and high-mobility pyrenes. BPyFBFFA was synthesized via the intermediates PyFA and BPyFA with iterative Friedel-Crafts reactions and Suzuki cross-coupling reactions. BPyFBFFA behaves as an efficient blue light-emitter without the low-energy green emission band. Complex diarylfluorenes (CDAFs) are promising candidates for nanoscale covalent organic frameworks and MOSs. Friedel-Crafts protocols offer versatile toolboxes for molecular architects to frame chemistry and materials, nanoscience, and molecular nanotechnology as well as molecular manufactures.

Original language	English
Article number	368202
Journal	Journal of Nanomaterials
Volume	2013
DOIs	https://doi.org/10.1155/2013/368202
State	Published - 2013
Externally published	Yes

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title = "Diarylfluorene-based shape-persistent organic nanomolecular frameworks via iterative Friedel-Crafts protocol toward multicomponent organic semiconductors",

abstract = "We describe bottom-up fluorenol approach to create soluble covalent organic nanomolecular architectures (ONAs) as potential multicomponent organic semiconductors (MOSs). BPyFBFFA as a typical model of ONAs and MOSs exhibits a persistent chair-shaped geometric structure that consists of hole-transporting triphenylamine (TPA), high-efficiency terfluorene, and high-mobility pyrenes. BPyFBFFA was synthesized via the intermediates PyFA and BPyFA with iterative Friedel-Crafts reactions and Suzuki cross-coupling reactions. BPyFBFFA behaves as an efficient blue light-emitter without the low-energy green emission band. Complex diarylfluorenes (CDAFs) are promising candidates for nanoscale covalent organic frameworks and MOSs. Friedel-Crafts protocols offer versatile toolboxes for molecular architects to frame chemistry and materials, nanoscience, and molecular nanotechnology as well as molecular manufactures.",

author = "Zhang, {Guang Wei} and Long Wang and Xie, {Ling Hai} and Hou, {Xiao Ya} and Liu, {Zheng Dong} and Wei Huang",

year = "2013",

doi = "10.1155/2013/368202",

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journal = "Journal of Nanomaterials",

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AU - Zhang, Guang Wei

AU - Wang, Long

AU - Xie, Ling Hai

AU - Hou, Xiao Ya

AU - Liu, Zheng Dong

AU - Huang, Wei

PY - 2013

Y1 - 2013

N2 - We describe bottom-up fluorenol approach to create soluble covalent organic nanomolecular architectures (ONAs) as potential multicomponent organic semiconductors (MOSs). BPyFBFFA as a typical model of ONAs and MOSs exhibits a persistent chair-shaped geometric structure that consists of hole-transporting triphenylamine (TPA), high-efficiency terfluorene, and high-mobility pyrenes. BPyFBFFA was synthesized via the intermediates PyFA and BPyFA with iterative Friedel-Crafts reactions and Suzuki cross-coupling reactions. BPyFBFFA behaves as an efficient blue light-emitter without the low-energy green emission band. Complex diarylfluorenes (CDAFs) are promising candidates for nanoscale covalent organic frameworks and MOSs. Friedel-Crafts protocols offer versatile toolboxes for molecular architects to frame chemistry and materials, nanoscience, and molecular nanotechnology as well as molecular manufactures.

AB - We describe bottom-up fluorenol approach to create soluble covalent organic nanomolecular architectures (ONAs) as potential multicomponent organic semiconductors (MOSs). BPyFBFFA as a typical model of ONAs and MOSs exhibits a persistent chair-shaped geometric structure that consists of hole-transporting triphenylamine (TPA), high-efficiency terfluorene, and high-mobility pyrenes. BPyFBFFA was synthesized via the intermediates PyFA and BPyFA with iterative Friedel-Crafts reactions and Suzuki cross-coupling reactions. BPyFBFFA behaves as an efficient blue light-emitter without the low-energy green emission band. Complex diarylfluorenes (CDAFs) are promising candidates for nanoscale covalent organic frameworks and MOSs. Friedel-Crafts protocols offer versatile toolboxes for molecular architects to frame chemistry and materials, nanoscience, and molecular nanotechnology as well as molecular manufactures.

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Diarylfluorene-based shape-persistent organic nanomolecular frameworks via iterative Friedel-Crafts protocol toward multicomponent organic semiconductors

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