Cobaltocenium-containing poly(carbazole)s towards alkaline-stable anion exchange membranes via post-polymerization modification

Jin Chen; Jing Yan; Weihong Yang; Yunxin Xu; Rui Chi; Qiuyu Zhang; Yi Yan

doi:10.1039/d4se00888j

Cobaltocenium-containing poly(carbazole)s towards alkaline-stable anion exchange membranes via post-polymerization modification

Jin Chen, Jing Yan, Weihong Yang, Yunxin Xu, Rui Chi, Qiuyu Zhang, Yi Yan

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Robust alkali-resistant cobaltocenium-containing poly(carbazole)s are prepared via the combination of superacid-catalyzed polyhydroxyalkylation and CuAAC-based post-polymerization modification. The prepared cobaltocenium-containing AEMs show a hydroxide conductivity of up to 127.2 mS cm⁻¹ at 80 °C and a conductivity retention of more than 95.0% after soaking in 1 M NaOH for 2500 h.

Original language	English
Pages (from-to)	4767-4771
Number of pages	5
Journal	Sustainable Energy and Fuels
Volume	8
Issue number	20
DOIs	https://doi.org/10.1039/d4se00888j
State	Published - 13 Sep 2024

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10.1039/d4se00888j

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title = "Cobaltocenium-containing poly(carbazole)s towards alkaline-stable anion exchange membranes via post-polymerization modification",

abstract = "Robust alkali-resistant cobaltocenium-containing poly(carbazole)s are prepared via the combination of superacid-catalyzed polyhydroxyalkylation and CuAAC-based post-polymerization modification. The prepared cobaltocenium-containing AEMs show a hydroxide conductivity of up to 127.2 mS cm−1 at 80 °C and a conductivity retention of more than 95.0% after soaking in 1 M NaOH for 2500 h.",

author = "Jin Chen and Jing Yan and Weihong Yang and Yunxin Xu and Rui Chi and Qiuyu Zhang and Yi Yan",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

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T1 - Cobaltocenium-containing poly(carbazole)s towards alkaline-stable anion exchange membranes via post-polymerization modification

AU - Chen, Jin

AU - Yan, Jing

AU - Yang, Weihong

AU - Xu, Yunxin

AU - Chi, Rui

AU - Zhang, Qiuyu

AU - Yan, Yi

PY - 2024/9/13

Y1 - 2024/9/13

N2 - Robust alkali-resistant cobaltocenium-containing poly(carbazole)s are prepared via the combination of superacid-catalyzed polyhydroxyalkylation and CuAAC-based post-polymerization modification. The prepared cobaltocenium-containing AEMs show a hydroxide conductivity of up to 127.2 mS cm−1 at 80 °C and a conductivity retention of more than 95.0% after soaking in 1 M NaOH for 2500 h.

AB - Robust alkali-resistant cobaltocenium-containing poly(carbazole)s are prepared via the combination of superacid-catalyzed polyhydroxyalkylation and CuAAC-based post-polymerization modification. The prepared cobaltocenium-containing AEMs show a hydroxide conductivity of up to 127.2 mS cm−1 at 80 °C and a conductivity retention of more than 95.0% after soaking in 1 M NaOH for 2500 h.

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U2 - 10.1039/d4se00888j

DO - 10.1039/d4se00888j

M3 - 文章

AN - SCOPUS:85204710988

SN - 2398-4902

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SP - 4767

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JO - Sustainable Energy and Fuels

JF - Sustainable Energy and Fuels

IS - 20

ER -

Cobaltocenium-containing poly(carbazole)s towards alkaline-stable anion exchange membranes via post-polymerization modification

Abstract

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