Abstract
As-synthesized Au nanoparticles (NPs) composed of bone-like and rod shapes and a minority of cube and irregular spheres, generating three localized surface plasmon resonance (LSPR) peaks of 525, 575, and 775 nm, were doped into poly(3, 4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) layer and realized a power conversion efficiency of as high as 9.26% in our polymer solar cells. Optical, electrical, and morphology changes induced by Au NPs were analyzed and results demonstrate that the outstanding device performance is mainly attributed to the LSPR- and scattering-induced absorption enhancement in the active layer. Besides, mixed Au NPs also decreased the bulk resistance of PEDOT:PSS, which is found to facilitate hole transport and collection.
Original language | English |
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Pages (from-to) | 50-58 |
Number of pages | 9 |
Journal | Optics Communications |
Volume | 362 |
DOIs | |
State | Published - 1 Mar 2016 |
Externally published | Yes |
Keywords
- Au nanoparticle
- Localized surface plasmon resonance
- Polymer solar cells
- Scattering