Biomass-derived N-doped porous two-dimensional carbon nanosheets supported ruthenium as effective catalysts for the selective hydrogenation of quinolines under mild conditions

Yueling Cao; Liang Ding; Zegang Qiu; Hepeng Zhang

doi:10.1016/j.catcom.2020.106048

Biomass-derived N-doped porous two-dimensional carbon nanosheets supported ruthenium as effective catalysts for the selective hydrogenation of quinolines under mild conditions

Yueling Cao, Liang Ding, Zegang Qiu, Hepeng Zhang

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Biomass-derived N-doped porous two-dimensional carbon nanosheets (NPCNs) with high surface area and pore volume were fabricated by using graphitic carbon nitride (g-C₃N₄) as both template and nitrogen source. The NPCNs were found to be promising supports to immobilize Ru nanoparticles (Ru/NPCNs), and Ru/NPCNs exhibit excellent catalytic performance for quinoline hydrogenation. 98.3% conversion and 96.1% selectivity were obtained within 3.5 h at 40 °C and 1 MPa H₂, which is far better than traditionally materials supported Ru catalysts. This work may provide a new choice for the synthesis of porous two-dimensional carbon nanosheets that can be used as catalyst support.

Original language	English
Article number	106048
Journal	Catalysis Communications
Volume	143
DOIs	https://doi.org/10.1016/j.catcom.2020.106048
State	Published - 5 Aug 2020

Keywords

N-doped carbon
Porous two-dimensional carbon nanosheets
Quinoline
Ru catalyst
Selective hydrogenation

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10.1016/j.catcom.2020.106048

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title = "Biomass-derived N-doped porous two-dimensional carbon nanosheets supported ruthenium as effective catalysts for the selective hydrogenation of quinolines under mild conditions",

abstract = "Biomass-derived N-doped porous two-dimensional carbon nanosheets (NPCNs) with high surface area and pore volume were fabricated by using graphitic carbon nitride (g-C3N4) as both template and nitrogen source. The NPCNs were found to be promising supports to immobilize Ru nanoparticles (Ru/NPCNs), and Ru/NPCNs exhibit excellent catalytic performance for quinoline hydrogenation. 98.3% conversion and 96.1% selectivity were obtained within 3.5 h at 40 °C and 1 MPa H2, which is far better than traditionally materials supported Ru catalysts. This work may provide a new choice for the synthesis of porous two-dimensional carbon nanosheets that can be used as catalyst support.",

keywords = "N-doped carbon, Porous two-dimensional carbon nanosheets, Quinoline, Ru catalyst, Selective hydrogenation",

author = "Yueling Cao and Liang Ding and Zegang Qiu and Hepeng Zhang",

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doi = "10.1016/j.catcom.2020.106048",

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T1 - Biomass-derived N-doped porous two-dimensional carbon nanosheets supported ruthenium as effective catalysts for the selective hydrogenation of quinolines under mild conditions

AU - Cao, Yueling

AU - Ding, Liang

AU - Qiu, Zegang

AU - Zhang, Hepeng

PY - 2020/8/5

Y1 - 2020/8/5

N2 - Biomass-derived N-doped porous two-dimensional carbon nanosheets (NPCNs) with high surface area and pore volume were fabricated by using graphitic carbon nitride (g-C3N4) as both template and nitrogen source. The NPCNs were found to be promising supports to immobilize Ru nanoparticles (Ru/NPCNs), and Ru/NPCNs exhibit excellent catalytic performance for quinoline hydrogenation. 98.3% conversion and 96.1% selectivity were obtained within 3.5 h at 40 °C and 1 MPa H2, which is far better than traditionally materials supported Ru catalysts. This work may provide a new choice for the synthesis of porous two-dimensional carbon nanosheets that can be used as catalyst support.

AB - Biomass-derived N-doped porous two-dimensional carbon nanosheets (NPCNs) with high surface area and pore volume were fabricated by using graphitic carbon nitride (g-C3N4) as both template and nitrogen source. The NPCNs were found to be promising supports to immobilize Ru nanoparticles (Ru/NPCNs), and Ru/NPCNs exhibit excellent catalytic performance for quinoline hydrogenation. 98.3% conversion and 96.1% selectivity were obtained within 3.5 h at 40 °C and 1 MPa H2, which is far better than traditionally materials supported Ru catalysts. This work may provide a new choice for the synthesis of porous two-dimensional carbon nanosheets that can be used as catalyst support.

KW - N-doped carbon

KW - Porous two-dimensional carbon nanosheets

KW - Quinoline

KW - Ru catalyst

KW - Selective hydrogenation

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DO - 10.1016/j.catcom.2020.106048

M3 - 文章

AN - SCOPUS:85085315062

SN - 1566-7367

VL - 143

JO - Catalysis Communications

JF - Catalysis Communications

M1 - 106048

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Biomass-derived N-doped porous two-dimensional carbon nanosheets supported ruthenium as effective catalysts for the selective hydrogenation of quinolines under mild conditions

Abstract

Keywords

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