TY - JOUR
T1 - Bioinspired synthesis of high-performance nanocomposite imprinted membrane by a polydopamine-assisted metal-organic method
AU - Wu, Yilin
AU - Liu, Xinlin
AU - Cui, Jiuyun
AU - Meng, Minjia
AU - Dai, Jiangdong
AU - Li, Chunxiang
AU - Yan, Yongsheng
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017/2/5
Y1 - 2017/2/5
N2 - Significant efforts have been focused on the functionalization and simplification of membrane-associated molecularly imprinted materials, which can rapidly recognize and separate specific compound. However, issues such as low permselectivity and unstable composite structures are restricting it from developing stage to a higher level. In this work, with the bioinspired design of polydopamine (pDA)-assisted inorganic film, we present a novel molecular imprinting strategy to integrate multilevel nanocomposites (Ag/pDA) into the porous membrane structure. The molecularly imprinted nanocomposite membranes were then obtained through an in situ photoinitiated ATRP method by using tetracycline (TC) as the template molecule. Importantly, attributing to the formation of the Ag/pDA-based TC-imprinted layers, largely enhance TC-rebinding capacity (35.41 mg/g), adsorption selectivity and structural stability (still maintained 92.1% of the maximum adsorption capacity after 10 cycling operations) could been easily achieved. Moreover, largely enhanced permselectivity performance toward template molecule (the permeability factor β values were also more than 5.95) was also obtained. Finally, all synthesis methods were conducted in aqueous solution at ambient temperature, which was environmental friendly for scaling up without causing pollution.
AB - Significant efforts have been focused on the functionalization and simplification of membrane-associated molecularly imprinted materials, which can rapidly recognize and separate specific compound. However, issues such as low permselectivity and unstable composite structures are restricting it from developing stage to a higher level. In this work, with the bioinspired design of polydopamine (pDA)-assisted inorganic film, we present a novel molecular imprinting strategy to integrate multilevel nanocomposites (Ag/pDA) into the porous membrane structure. The molecularly imprinted nanocomposite membranes were then obtained through an in situ photoinitiated ATRP method by using tetracycline (TC) as the template molecule. Importantly, attributing to the formation of the Ag/pDA-based TC-imprinted layers, largely enhance TC-rebinding capacity (35.41 mg/g), adsorption selectivity and structural stability (still maintained 92.1% of the maximum adsorption capacity after 10 cycling operations) could been easily achieved. Moreover, largely enhanced permselectivity performance toward template molecule (the permeability factor β values were also more than 5.95) was also obtained. Finally, all synthesis methods were conducted in aqueous solution at ambient temperature, which was environmental friendly for scaling up without causing pollution.
KW - Bioinspired nanocomposite synthesis
KW - Molecularly imprinted membrane
KW - Selective recognition and separation
KW - TC
UR - http://www.scopus.com/inward/record.url?scp=84997207070&partnerID=8YFLogxK
U2 - 10.1016/j.jhazmat.2016.10.030
DO - 10.1016/j.jhazmat.2016.10.030
M3 - 文章
C2 - 27776858
AN - SCOPUS:84997207070
SN - 0304-3894
VL - 323
SP - 663
EP - 673
JO - Journal of Hazardous Materials
JF - Journal of Hazardous Materials
ER -