TY - JOUR
T1 - Band Gap Modulation Enabled by TCNQ Loading in a Ru-Based Metal-Organic Framework for Enhanced Near-Infrared Absorption and Photothermal Conversion
AU - Zhang, Tao
AU - Cao, Jian Wei
AU - Jiang, Xue
AU - Chen, Juan
AU - Wang, Teng
AU - Chen, Kai Jie
N1 - Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/2/3
Y1 - 2021/2/3
N2 - In this work, a band insertion strategy by 7,7,8,8-tetracyanoquinododimethane (TCNQ) loading is applied to modulate the band gap of a ruthenium metal-organic framework, [Ru3(btc)2Cl1.5] (btc = 1,3,5-benzenetricarboxylate, Ru-MOF). After TCNQ loading, TCNQ@Ru-MOF exhibited a narrower band gap of 0.68 eV than 2.06 eV of pristine Ru-MOF, consistent with observations in corresponding density functional theory calculation. Furthermore, under irradiation of 980 nm laser, an enhanced photothermal property with a photothermal conversion efficiency of 29.1% was achieved by TCNQ@Ru-MOF.
AB - In this work, a band insertion strategy by 7,7,8,8-tetracyanoquinododimethane (TCNQ) loading is applied to modulate the band gap of a ruthenium metal-organic framework, [Ru3(btc)2Cl1.5] (btc = 1,3,5-benzenetricarboxylate, Ru-MOF). After TCNQ loading, TCNQ@Ru-MOF exhibited a narrower band gap of 0.68 eV than 2.06 eV of pristine Ru-MOF, consistent with observations in corresponding density functional theory calculation. Furthermore, under irradiation of 980 nm laser, an enhanced photothermal property with a photothermal conversion efficiency of 29.1% was achieved by TCNQ@Ru-MOF.
UR - http://www.scopus.com/inward/record.url?scp=85100254555&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.0c01447
DO - 10.1021/acs.cgd.0c01447
M3 - 文章
AN - SCOPUS:85100254555
SN - 1528-7483
VL - 21
SP - 729
EP - 734
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 2
ER -