Achieving high efficiency silicon-carbon nanotube heterojunction solar cells by acid doping

Yi Jia, Anyuan Cao, Xi Bai, Zhen Li, Luhui Zhang, Ning Guo, Jinquan Wei, Kunlin Wang, Hongwei Zhu, Dehai Wu, P. M. Ajayan

Research output: Contribution to journalArticlepeer-review

232 Scopus citations

Abstract

Various approaches to improve the efficiency of solar cells have followed the integration of nanomaterials into Si-based photovoltaic devices. Here, we achieve 13.8% efficiency solar cells by combining carbon nanotubes and Si and doping with dilute HNO3. Acid infiltration of nanotube networks significantly boost the cell efficiency by reducing the internal resistance that improves fill factor and by forming photoelectrochemical units that enhance charge separation and transport. Compared to conventional Si cells, the fabrication process is greatly simplified, simply involving the transfer of a porous semiconductor-rich nanotube film onto an n-type crystalline Si wafer followed by acid infiltration.

Original languageEnglish
Pages (from-to)1901-1905
Number of pages5
JournalNano Letters
Volume11
Issue number5
DOIs
StatePublished - 11 May 2011
Externally publishedYes

Keywords

  • Carbon nanotube
  • acid doping
  • photoelectrochemical cells
  • solar cell

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