TY - JOUR
T1 - A three-dimensional porous metal-organic framework based on cyano unit and 1,4-bis(1,2,4-triazol-1-yl)butane (btb)
T2 - {[Cu 8(btb) 2(CN) 8]·3H 2O} n
AU - Zhou, Xin Hui
AU - Li, Hong Hui
AU - Huang, Wei
PY - 2012/1/15
Y1 - 2012/1/15
N2 - The title coordination polymer 1, {[Cu 8(btb) 2(CN) 8]·3H 2O} n (btb = 1,4-bis(1,2,4-triazol- 1-yl)butane), has been hydrothermally synthesized and structurally characterized by singlecrystal X-ray diffraction. Complex 1 crystallizes in monoclinic, space group C2/c with a = 1.2938(3), b = 1.9422(5), c = 0.9406(2) nm, β = 121.891(4)°, V = 2.0066(9) nm 3, C 24H 30Cu 8N 20O 3, M r = 1155.00, D c = 1.912 g/cm 3, μ(MoKα) = 4.209 mm -1, F(000) = 1140, GOF = 1.184, Z = 2, the final R = 0.0634 and wR = 0.1503 for I > 2o(I). In complex 1, one-dimensional CuCN zigzag chains are linked by triazolyl groups of btb ligands to form two-dimensional networks, which are further bridged by 1,4-butyl moieties of btb ligands to fabricate a three-dimensional order framework, in which one-dimensional ellipsoid-like channels are observed.
AB - The title coordination polymer 1, {[Cu 8(btb) 2(CN) 8]·3H 2O} n (btb = 1,4-bis(1,2,4-triazol- 1-yl)butane), has been hydrothermally synthesized and structurally characterized by singlecrystal X-ray diffraction. Complex 1 crystallizes in monoclinic, space group C2/c with a = 1.2938(3), b = 1.9422(5), c = 0.9406(2) nm, β = 121.891(4)°, V = 2.0066(9) nm 3, C 24H 30Cu 8N 20O 3, M r = 1155.00, D c = 1.912 g/cm 3, μ(MoKα) = 4.209 mm -1, F(000) = 1140, GOF = 1.184, Z = 2, the final R = 0.0634 and wR = 0.1503 for I > 2o(I). In complex 1, one-dimensional CuCN zigzag chains are linked by triazolyl groups of btb ligands to form two-dimensional networks, which are further bridged by 1,4-butyl moieties of btb ligands to fabricate a three-dimensional order framework, in which one-dimensional ellipsoid-like channels are observed.
KW - 1,4-Bis(1,2,4-triazol-1-yl)butane
KW - Complex
KW - Cu
KW - Cyano
KW - Metal-organic framework (MOF)
UR - http://www.scopus.com/inward/record.url?scp=84862958523&partnerID=8YFLogxK
M3 - 文章
AN - SCOPUS:84862958523
SN - 0254-5861
VL - 31
SP - 33
EP - 38
JO - Jiegou Huaxue
JF - Jiegou Huaxue
IS - 1
ER -