A supramolecular hyperbranched polymer with multi-responsiveness constructed by pillar[5]arene-based host-guest recognition and its application in the breath figure method

Yuezhou Liu; Yingyi Zhang; Huangtianzhi Zhu; Hu Wang; Wei Tian; Bingbing Shi

doi:10.1039/c8qm00220g

A supramolecular hyperbranched polymer with multi-responsiveness constructed by pillar[5]arene-based host-guest recognition and its application in the breath figure method

Yuezhou Liu, Yingyi Zhang, Huangtianzhi Zhu, Hu Wang, Wei Tian, Bingbing Shi

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

In this work, a disulfide-bridged bispillar[5]arene (A ₂ ) and tritopic neutral guest molecule (B ₃ ) were synthesized and used to construct supramolecular hyperbranched polymers (SHPs) utilizing pillar[5]arene-based host-guest interactions. In particular, a supramolecular gel with interesting reversible gel-sol transition in response to a temperature change and redox owing to the dynamic host-guest complexation and the characteristics of the disulfide bond can be obtained via the self-assembly behavior of the SHPs under high concentration. Moreover, honeycomb-patterned films can be successfully prepared by utilizing the breath figure method.

Original language	English
Pages (from-to)	1568-1573
Number of pages	6
Journal	Materials Chemistry Frontiers
Volume	2
Issue number	8
DOIs	https://doi.org/10.1039/c8qm00220g
State	Published - Aug 2018

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title = "A supramolecular hyperbranched polymer with multi-responsiveness constructed by pillar[5]arene-based host-guest recognition and its application in the breath figure method",

abstract = " In this work, a disulfide-bridged bispillar[5]arene (A 2 ) and tritopic neutral guest molecule (B 3 ) were synthesized and used to construct supramolecular hyperbranched polymers (SHPs) utilizing pillar[5]arene-based host-guest interactions. In particular, a supramolecular gel with interesting reversible gel-sol transition in response to a temperature change and redox owing to the dynamic host-guest complexation and the characteristics of the disulfide bond can be obtained via the self-assembly behavior of the SHPs under high concentration. Moreover, honeycomb-patterned films can be successfully prepared by utilizing the breath figure method.",

author = "Yuezhou Liu and Yingyi Zhang and Huangtianzhi Zhu and Hu Wang and Wei Tian and Bingbing Shi",

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AU - Liu, Yuezhou

AU - Zhang, Yingyi

AU - Zhu, Huangtianzhi

AU - Wang, Hu

AU - Tian, Wei

AU - Shi, Bingbing

PY - 2018/8

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N2 - In this work, a disulfide-bridged bispillar[5]arene (A 2 ) and tritopic neutral guest molecule (B 3 ) were synthesized and used to construct supramolecular hyperbranched polymers (SHPs) utilizing pillar[5]arene-based host-guest interactions. In particular, a supramolecular gel with interesting reversible gel-sol transition in response to a temperature change and redox owing to the dynamic host-guest complexation and the characteristics of the disulfide bond can be obtained via the self-assembly behavior of the SHPs under high concentration. Moreover, honeycomb-patterned films can be successfully prepared by utilizing the breath figure method.

AB - In this work, a disulfide-bridged bispillar[5]arene (A 2 ) and tritopic neutral guest molecule (B 3 ) were synthesized and used to construct supramolecular hyperbranched polymers (SHPs) utilizing pillar[5]arene-based host-guest interactions. In particular, a supramolecular gel with interesting reversible gel-sol transition in response to a temperature change and redox owing to the dynamic host-guest complexation and the characteristics of the disulfide bond can be obtained via the self-assembly behavior of the SHPs under high concentration. Moreover, honeycomb-patterned films can be successfully prepared by utilizing the breath figure method.

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A supramolecular hyperbranched polymer with multi-responsiveness constructed by pillar[5]arene-based host-guest recognition and its application in the breath figure method

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