A study of 2-(dibutylaminomethyl)-thiobenzimidazole as an oil additive

Junyan Zhang; Weimin Liu; Qunji Xue

doi:10.1016/S0043-1648(99)00158-1

A study of 2-(dibutylaminomethyl)-thiobenzimidazole as an oil additive

Junyan Zhang, Weimin Liu, Qunji Xue

CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A Mannich condensation compound of 2-(dibutylaminomethyl)-thiobenzimidazole was synthesized and its antiwear (AW) behavior as an additive in a paraffinic base oil was evaluated using a four-ball tester. To investigate the role of scavenging free hydrogen radicals of the novel compound, a thermal degradation test was conducted using differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA) (commercialism). The nature of the film formed on the rubbed surface was investigated by X-ray photoelectron spectroscopy (XPS) analysis. On the basis of the experimental results, the novel additive showed good AW ability and good thermal stability. The results of XPS analyses illustrate that the prepared compound as an additive in paraffinic base oil forms a protective film containing ferric sulfide, ferric sulfate and compounds containing sulfur and nitrogen on the rubbed surface.

Original language	English
Pages (from-to)	279-284
Number of pages	6
Journal	Wear
Volume	231
Issue number	2
DOIs	https://doi.org/10.1016/S0043-1648(99)00158-1
State	Published - Jul 1999
Externally published	Yes

Keywords

2-(Dibutylaminomethyl)-thiobenzimidazole
Additive
Antiwear
Thermal analysis
XPS analyses

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10.1016/S0043-1648(99)00158-1

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title = "A study of 2-(dibutylaminomethyl)-thiobenzimidazole as an oil additive",

abstract = "A Mannich condensation compound of 2-(dibutylaminomethyl)-thiobenzimidazole was synthesized and its antiwear (AW) behavior as an additive in a paraffinic base oil was evaluated using a four-ball tester. To investigate the role of scavenging free hydrogen radicals of the novel compound, a thermal degradation test was conducted using differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA) (commercialism). The nature of the film formed on the rubbed surface was investigated by X-ray photoelectron spectroscopy (XPS) analysis. On the basis of the experimental results, the novel additive showed good AW ability and good thermal stability. The results of XPS analyses illustrate that the prepared compound as an additive in paraffinic base oil forms a protective film containing ferric sulfide, ferric sulfate and compounds containing sulfur and nitrogen on the rubbed surface.",

keywords = "2-(Dibutylaminomethyl)-thiobenzimidazole, Additive, Antiwear, Thermal analysis, XPS analyses",

author = "Junyan Zhang and Weimin Liu and Qunji Xue",

year = "1999",

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T1 - A study of 2-(dibutylaminomethyl)-thiobenzimidazole as an oil additive

AU - Zhang, Junyan

AU - Liu, Weimin

AU - Xue, Qunji

PY - 1999/7

Y1 - 1999/7

N2 - A Mannich condensation compound of 2-(dibutylaminomethyl)-thiobenzimidazole was synthesized and its antiwear (AW) behavior as an additive in a paraffinic base oil was evaluated using a four-ball tester. To investigate the role of scavenging free hydrogen radicals of the novel compound, a thermal degradation test was conducted using differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA) (commercialism). The nature of the film formed on the rubbed surface was investigated by X-ray photoelectron spectroscopy (XPS) analysis. On the basis of the experimental results, the novel additive showed good AW ability and good thermal stability. The results of XPS analyses illustrate that the prepared compound as an additive in paraffinic base oil forms a protective film containing ferric sulfide, ferric sulfate and compounds containing sulfur and nitrogen on the rubbed surface.

AB - A Mannich condensation compound of 2-(dibutylaminomethyl)-thiobenzimidazole was synthesized and its antiwear (AW) behavior as an additive in a paraffinic base oil was evaluated using a four-ball tester. To investigate the role of scavenging free hydrogen radicals of the novel compound, a thermal degradation test was conducted using differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA) (commercialism). The nature of the film formed on the rubbed surface was investigated by X-ray photoelectron spectroscopy (XPS) analysis. On the basis of the experimental results, the novel additive showed good AW ability and good thermal stability. The results of XPS analyses illustrate that the prepared compound as an additive in paraffinic base oil forms a protective film containing ferric sulfide, ferric sulfate and compounds containing sulfur and nitrogen on the rubbed surface.

KW - 2-(Dibutylaminomethyl)-thiobenzimidazole

KW - Additive

KW - Antiwear

KW - Thermal analysis

KW - XPS analyses

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U2 - 10.1016/S0043-1648(99)00158-1

DO - 10.1016/S0043-1648(99)00158-1

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ER -

A study of 2-(dibutylaminomethyl)-thiobenzimidazole as an oil additive

Abstract

Keywords

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