TY - JOUR
T1 - A novel dielectric barrier discharge reactor with photocatalytic electrode based on sintered metal fibers for abatement of xylene
AU - Ye, Zhiping
AU - Wang, Chunxia
AU - Shao, Zhenhua
AU - Ye, Qing
AU - He, Yi
AU - Shi, Yao
PY - 2012/11/30
Y1 - 2012/11/30
N2 - A novel dielectric barrier discharge (DBD) reactor was made for the abatement of xylene. This reactor has a photocatalytic electrode prepared by a modified anodic oxidation method which was proposed in this work. The photocatalytic electrode has nano-TiO2 deposited on sintered metal fiber (SMF). The reactor using the nano-TiO2/SMF electrode shows much better performance in abating xylene compared with reactors using other electrodes such as resistance wire or SMF. The conversion ratio of xylene reaches 92.7% in the novel reactor at a relatively voltage (23.6kV). This ratio is much higher than the conversion ratios of xylene in the traditional reactors with resistance wire or SMF electrodes, which are ∼64.7%. The selectivity of CO2 of the reactor using the nano-TiO2/SMF electrode (300pps, 23.6kV) was observed to be 86.6%, which is about twice as large as that of a traditional reactor using a resistance wire electrode. If a traditional DBD reactor is replaced by the novel reactor, at the same specific input energy, the energy yield can increase from 0.391 to 0.556mg/kJ. Finally, the xylene decomposition mechanism with the nano-TiO2/SMF electrode was also briefly discussed.
AB - A novel dielectric barrier discharge (DBD) reactor was made for the abatement of xylene. This reactor has a photocatalytic electrode prepared by a modified anodic oxidation method which was proposed in this work. The photocatalytic electrode has nano-TiO2 deposited on sintered metal fiber (SMF). The reactor using the nano-TiO2/SMF electrode shows much better performance in abating xylene compared with reactors using other electrodes such as resistance wire or SMF. The conversion ratio of xylene reaches 92.7% in the novel reactor at a relatively voltage (23.6kV). This ratio is much higher than the conversion ratios of xylene in the traditional reactors with resistance wire or SMF electrodes, which are ∼64.7%. The selectivity of CO2 of the reactor using the nano-TiO2/SMF electrode (300pps, 23.6kV) was observed to be 86.6%, which is about twice as large as that of a traditional reactor using a resistance wire electrode. If a traditional DBD reactor is replaced by the novel reactor, at the same specific input energy, the energy yield can increase from 0.391 to 0.556mg/kJ. Finally, the xylene decomposition mechanism with the nano-TiO2/SMF electrode was also briefly discussed.
KW - Anodic oxidation
KW - Dielectric barrier discharge
KW - Nano-TiO/SMF electrode
KW - Ti
KW - Xylene
UR - http://www.scopus.com/inward/record.url?scp=84868495609&partnerID=8YFLogxK
U2 - 10.1016/j.jhazmat.2012.09.033
DO - 10.1016/j.jhazmat.2012.09.033
M3 - 文章
C2 - 23040659
AN - SCOPUS:84868495609
SN - 0304-3894
VL - 241-242
SP - 216
EP - 223
JO - Journal of Hazardous Materials
JF - Journal of Hazardous Materials
ER -