A new acentric heterometallic inorganic-organic hybrid framework [ZnK2 (m-BDC)2 (H2O)2]n: Fluorescent, NLO and ferroelectric properties

Li Ping Xue; Yue Cheng Liu; Yun Hu Han; Qi Peng Li; C. B. Tian; Ping Lin; Shao Wu Du

A new acentric heterometallic inorganic-organic hybrid framework [ZnK₂ (m-BDC)₂ (H₂O)₂]n: Fluorescent, NLO and ferroelectric properties

Li Ping Xue, Yue Cheng Liu, Yun Hu Han, Qi Peng Li, C. B. Tian, Ping Lin, Shao Wu Du

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Solvothermal reactions of Zn(NO₃)₂·6H₂O with isophthalic acid in the presence of potassium nitrate lead to an acentric three-dimensional (3D) hetero-metallic inorganic-organic hybrid framework [ZnK₂ (m-BDC) ₂ (H₂O)₂]_n (1, m-H₂BDC = benzene-1, 3-dicarboxylic acid). The crystal was characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction analysis. Complex 1 is of orthogonal crystal system, acentric space group Cmc2₁ with a = 19.764(6), b = 19.948(6), c = 12.039(4) Å, V = 4746(3) Å³, Z = 4, C₃₂H₂₀O₁₉K₄Zn₂, Mr = 995.66, D_c = 1.393 g/cm³, F(000) = 2000 and μ = 1.426 mm^-1. The final R = 0.0761 and wR = 0.1841. The crystal exhibits remarkable blue luminescence emissions with high quantum yield of 56.02% and displays modest powder SHG efficiency of about 0.7 times that produced by a potassium dihydrogen phosphate (KDP) powder. In addition, it also exhibits potential ferroelectric property.

Original language	English
Pages (from-to)	1360-1366
Number of pages	7
Journal	Jiegou Huaxue
Volume	33
Issue number	9
State	Published - 15 Sep 2014
Externally published	Yes

Keywords

Ferroelectric
Heterometallic
Photoluminescence
Solvothermal synthesis

Cite this

@article{20dfa53886754146893d28b22da13e81,

title = "A new acentric heterometallic inorganic-organic hybrid framework [ZnK2 (m-BDC)2 (H2O)2]n: Fluorescent, NLO and ferroelectric properties",

abstract = "Solvothermal reactions of Zn(NO3)2·6H2O with isophthalic acid in the presence of potassium nitrate lead to an acentric three-dimensional (3D) hetero-metallic inorganic-organic hybrid framework [ZnK2 (m-BDC) 2 (H2O)2]n (1, m-H2BDC = benzene-1, 3-dicarboxylic acid). The crystal was characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction analysis. Complex 1 is of orthogonal crystal system, acentric space group Cmc21 with a = 19.764(6), b = 19.948(6), c = 12.039(4) {\AA}, V = 4746(3) {\AA}3, Z = 4, C32H20O19K4Zn2, Mr = 995.66, Dc = 1.393 g/cm3, F(000) = 2000 and μ = 1.426 mm-1. The final R = 0.0761 and wR = 0.1841. The crystal exhibits remarkable blue luminescence emissions with high quantum yield of 56.02% and displays modest powder SHG efficiency of about 0.7 times that produced by a potassium dihydrogen phosphate (KDP) powder. In addition, it also exhibits potential ferroelectric property.",

keywords = "Ferroelectric, Heterometallic, Photoluminescence, Solvothermal synthesis",

author = "Xue, {Li Ping} and Liu, {Yue Cheng} and Han, {Yun Hu} and Li, {Qi Peng} and Tian, {C. B.} and Ping Lin and Du, {Shao Wu}",

year = "2014",

month = sep,

day = "15",

language = "英语",

volume = "33",

pages = "1360--1366",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "9",

}

TY - JOUR

T1 - A new acentric heterometallic inorganic-organic hybrid framework [ZnK2 (m-BDC)2 (H2O)2]n

T2 - Fluorescent, NLO and ferroelectric properties

AU - Xue, Li Ping

AU - Liu, Yue Cheng

AU - Han, Yun Hu

AU - Li, Qi Peng

AU - Tian, C. B.

AU - Lin, Ping

AU - Du, Shao Wu

PY - 2014/9/15

Y1 - 2014/9/15

N2 - Solvothermal reactions of Zn(NO3)2·6H2O with isophthalic acid in the presence of potassium nitrate lead to an acentric three-dimensional (3D) hetero-metallic inorganic-organic hybrid framework [ZnK2 (m-BDC) 2 (H2O)2]n (1, m-H2BDC = benzene-1, 3-dicarboxylic acid). The crystal was characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction analysis. Complex 1 is of orthogonal crystal system, acentric space group Cmc21 with a = 19.764(6), b = 19.948(6), c = 12.039(4) Å, V = 4746(3) Å3, Z = 4, C32H20O19K4Zn2, Mr = 995.66, Dc = 1.393 g/cm3, F(000) = 2000 and μ = 1.426 mm-1. The final R = 0.0761 and wR = 0.1841. The crystal exhibits remarkable blue luminescence emissions with high quantum yield of 56.02% and displays modest powder SHG efficiency of about 0.7 times that produced by a potassium dihydrogen phosphate (KDP) powder. In addition, it also exhibits potential ferroelectric property.

AB - Solvothermal reactions of Zn(NO3)2·6H2O with isophthalic acid in the presence of potassium nitrate lead to an acentric three-dimensional (3D) hetero-metallic inorganic-organic hybrid framework [ZnK2 (m-BDC) 2 (H2O)2]n (1, m-H2BDC = benzene-1, 3-dicarboxylic acid). The crystal was characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction analysis. Complex 1 is of orthogonal crystal system, acentric space group Cmc21 with a = 19.764(6), b = 19.948(6), c = 12.039(4) Å, V = 4746(3) Å3, Z = 4, C32H20O19K4Zn2, Mr = 995.66, Dc = 1.393 g/cm3, F(000) = 2000 and μ = 1.426 mm-1. The final R = 0.0761 and wR = 0.1841. The crystal exhibits remarkable blue luminescence emissions with high quantum yield of 56.02% and displays modest powder SHG efficiency of about 0.7 times that produced by a potassium dihydrogen phosphate (KDP) powder. In addition, it also exhibits potential ferroelectric property.

KW - Ferroelectric

KW - Heterometallic

KW - Photoluminescence

KW - Solvothermal synthesis

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M3 - 文章

AN - SCOPUS:84908299401

SN - 0254-5861

VL - 33

SP - 1360

EP - 1366

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 9

ER -

A new acentric heterometallic inorganic-organic hybrid framework [ZnK₂ (m-BDC)₂ (H₂O)₂]n: Fluorescent, NLO and ferroelectric properties

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