A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C2H2/CO2Separation

Bao Yong Zhu; Tao Zhang; Chun Hui Li; Jian Wei Cao; Zhu Qing Zhang; Wei Qi; Guang Yin Wang; Zhi Hui Rong; Yu Wang; Kai Jie Chen

doi:10.1021/acs.inorgchem.2c00004

A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C₂H₂/CO₂Separation

Bao Yong Zhu, Tao Zhang, Chun Hui Li, Jian Wei Cao, Zhu Qing Zhang, Wei Qi, Guang Yin Wang, Zhi Hui Rong, Yu Wang, Kai Jie Chen

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc^2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni₃(μ₃-OH)(tdc)₃(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C₂H₂over CO₂in an efficient manner.

Original language	English
Pages (from-to)	4555-4560
Number of pages	6
Journal	Inorganic Chemistry
Volume	61
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.2c00004
State	Published - 21 Mar 2022

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title = "A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C2H2/CO2Separation",

abstract = "Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni3(μ3-OH)(tdc)3(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C2H2over CO2in an efficient manner.",

author = "Zhu, {Bao Yong} and Tao Zhang and Li, {Chun Hui} and Cao, {Jian Wei} and Zhang, {Zhu Qing} and Wei Qi and Wang, {Guang Yin} and Rong, {Zhi Hui} and Yu Wang and Chen, {Kai Jie}",

year = "2022",

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day = "21",

doi = "10.1021/acs.inorgchem.2c00004",

language = "英语",

volume = "61",

pages = "4555--4560",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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TY - JOUR

T1 - A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C2H2/CO2Separation

AU - Zhu, Bao Yong

AU - Zhang, Tao

AU - Li, Chun Hui

AU - Cao, Jian Wei

AU - Zhang, Zhu Qing

AU - Qi, Wei

AU - Wang, Guang Yin

AU - Rong, Zhi Hui

AU - Wang, Yu

AU - Chen, Kai Jie

PY - 2022/3/21

Y1 - 2022/3/21

N2 - Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni3(μ3-OH)(tdc)3(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C2H2over CO2in an efficient manner.

AB - Herein, by replacement of the linear terephthalate linker with the bending 2,5-thiophenedicarboxylate (tdc2-) linker in the typical (3,9)-connected metal-organic framework, with a reduced 8-connected hydroxyl-centered trinuclear cluster, a new (3,8)-connected network, [Ni3(μ3-OH)(tdc)3(tpp)] [DZU-1; tpp = 2,4,6-tris(4-pyridyl)pyridine], was synthesized. The modified pore environment enables DZU-1 to selectively adsorb C2H2over CO2in an efficient manner.

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U2 - 10.1021/acs.inorgchem.2c00004

DO - 10.1021/acs.inorgchem.2c00004

M3 - 文章

C2 - 35257588

AN - SCOPUS:85126547440

SN - 0020-1669

VL - 61

SP - 4555

EP - 4560

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

A (3,8)-Connected Metal-Organic Framework with Bending Dicarboxylate Linkers for C₂H₂/CO₂Separation

Abstract

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