1,2,3-Triazolium-based poly(acrylate ionic liquid)s

Rakhi Sood; Mona Marie Obadia; Bhanu Prakash Mudraboyina; Biao Zhang; Anatoli Serghei; Julien Bernard; Eric Drockenmuller

doi:10.1016/j.polymer.2014.04.017

1,2,3-Triazolium-based poly(acrylate ionic liquid)s

Rakhi Sood, Mona Marie Obadia, Bhanu Prakash Mudraboyina, Biao Zhang, Anatoli Serghei, Julien Bernard, Eric Drockenmuller

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (M_n = 7860 g mol^-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (T_g = -40 °C), high thermal stability (T_d10 = 325 °C) and anhydrous ionic conductivity of 4 × 10^-6 S cm^-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.

Original language	English
Pages (from-to)	3314-3319
Number of pages	6
Journal	Polymer
Volume	55
Issue number	16
DOIs	https://doi.org/10.1016/j.polymer.2014.04.017
State	Published - 5 Aug 2014
Externally published	Yes

Keywords

Click chemistry
Nitroxide-mediated radical polymerization
Poly(ionic liquid)s

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@article{84992e89fad842fab0d0d241890147aa,

title = "1,2,3-Triazolium-based poly(acrylate ionic liquid)s",

abstract = "Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (Mn = 7860 g mol-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (Tg = -40 °C), high thermal stability (Td10 = 325 °C) and anhydrous ionic conductivity of 4 × 10-6 S cm-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.",

keywords = "Click chemistry, Nitroxide-mediated radical polymerization, Poly(ionic liquid)s",

author = "Rakhi Sood and Obadia, {Mona Marie} and Mudraboyina, {Bhanu Prakash} and Biao Zhang and Anatoli Serghei and Julien Bernard and Eric Drockenmuller",

year = "2014",

month = aug,

day = "5",

doi = "10.1016/j.polymer.2014.04.017",

language = "英语",

volume = "55",

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TY - JOUR

T1 - 1,2,3-Triazolium-based poly(acrylate ionic liquid)s

AU - Sood, Rakhi

AU - Obadia, Mona Marie

AU - Mudraboyina, Bhanu Prakash

AU - Zhang, Biao

AU - Serghei, Anatoli

AU - Bernard, Julien

AU - Drockenmuller, Eric

PY - 2014/8/5

Y1 - 2014/8/5

N2 - Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (Mn = 7860 g mol-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (Tg = -40 °C), high thermal stability (Td10 = 325 °C) and anhydrous ionic conductivity of 4 × 10-6 S cm-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.

AB - Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (Mn = 7860 g mol-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (Tg = -40 °C), high thermal stability (Td10 = 325 °C) and anhydrous ionic conductivity of 4 × 10-6 S cm-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.

KW - Click chemistry

KW - Nitroxide-mediated radical polymerization

KW - Poly(ionic liquid)s

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U2 - 10.1016/j.polymer.2014.04.017

DO - 10.1016/j.polymer.2014.04.017

M3 - 文章

AN - SCOPUS:84905485722

SN - 0032-3861

VL - 55

SP - 3314

EP - 3319

JO - Polymer

JF - Polymer

IS - 16

ER -

1,2,3-Triazolium-based poly(acrylate ionic liquid)s

Abstract

Keywords

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