φ-Conjugated molecules based on truxene cores and pyrene substitution:Synthesis and properties

Chao Tang; Xu Dong Liu; Feng Liu; Xu Liang Wang; Hui Xu; Rui Lan Liu; Zhou Rong; Wei Huang

doi:10.3184/174751913X13639408275103

φ-Conjugated molecules based on truxene cores and pyrene substitution:Synthesis and properties

Chao Tang, Xu Dong Liu, Feng Liu, Xu Liang Wang, Hui Xu, Rui Lan Liu, Zhou Rong, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Two starburst molecules based on pyrene with truxene cores, PYT and PYET, have been designed and synthesised by Pd(0)-catalysed Suzuki coupling and Sonogashira coupling reactions, respectively. Due to the different conjugation length, the solution absorption and emission spectra of PYET in dilute THF were redshifted compared with those of PYT. The solid absorption and emission spectra of PYET were also redshifted. Their thermal decomposition temperatures (T _d) were over 400 °C, and the glass transition temperatures (T_g) were 96 and 124 °C, respectively, which showed that both materials possess good thermal stability. Electrochemical analysis implied that the HOMOs of PYET and PYT were similar.

Original language	English
Pages (from-to)	242-247
Number of pages	6
Journal	Journal of Chemical Research
Volume	37
Issue number	4
DOIs	https://doi.org/10.3184/174751913X13639408275103
State	Published - Apr 2013
Externally published	Yes

Keywords

Organic semiconductors
Pyrene
Starburst
Truxene

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10.3184/174751913X13639408275103

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title = "φ-Conjugated molecules based on truxene cores and pyrene substitution:Synthesis and properties",

abstract = "Two starburst molecules based on pyrene with truxene cores, PYT and PYET, have been designed and synthesised by Pd(0)-catalysed Suzuki coupling and Sonogashira coupling reactions, respectively. Due to the different conjugation length, the solution absorption and emission spectra of PYET in dilute THF were redshifted compared with those of PYT. The solid absorption and emission spectra of PYET were also redshifted. Their thermal decomposition temperatures (T d) were over 400 °C, and the glass transition temperatures (Tg) were 96 and 124 °C, respectively, which showed that both materials possess good thermal stability. Electrochemical analysis implied that the HOMOs of PYET and PYT were similar.",

keywords = "Organic semiconductors, Pyrene, Starburst, Truxene",

author = "Chao Tang and Liu, {Xu Dong} and Feng Liu and Wang, {Xu Liang} and Hui Xu and Liu, {Rui Lan} and Zhou Rong and Wei Huang",

year = "2013",

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doi = "10.3184/174751913X13639408275103",

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volume = "37",

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journal = "Journal of Chemical Research",

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T1 - φ-Conjugated molecules based on truxene cores and pyrene substitution:Synthesis and properties

AU - Tang, Chao

AU - Liu, Xu Dong

AU - Liu, Feng

AU - Wang, Xu Liang

AU - Xu, Hui

AU - Liu, Rui Lan

AU - Rong, Zhou

AU - Huang, Wei

PY - 2013/4

Y1 - 2013/4

N2 - Two starburst molecules based on pyrene with truxene cores, PYT and PYET, have been designed and synthesised by Pd(0)-catalysed Suzuki coupling and Sonogashira coupling reactions, respectively. Due to the different conjugation length, the solution absorption and emission spectra of PYET in dilute THF were redshifted compared with those of PYT. The solid absorption and emission spectra of PYET were also redshifted. Their thermal decomposition temperatures (T d) were over 400 °C, and the glass transition temperatures (Tg) were 96 and 124 °C, respectively, which showed that both materials possess good thermal stability. Electrochemical analysis implied that the HOMOs of PYET and PYT were similar.

AB - Two starburst molecules based on pyrene with truxene cores, PYT and PYET, have been designed and synthesised by Pd(0)-catalysed Suzuki coupling and Sonogashira coupling reactions, respectively. Due to the different conjugation length, the solution absorption and emission spectra of PYET in dilute THF were redshifted compared with those of PYT. The solid absorption and emission spectra of PYET were also redshifted. Their thermal decomposition temperatures (T d) were over 400 °C, and the glass transition temperatures (Tg) were 96 and 124 °C, respectively, which showed that both materials possess good thermal stability. Electrochemical analysis implied that the HOMOs of PYET and PYT were similar.

KW - Organic semiconductors

KW - Pyrene

KW - Starburst

KW - Truxene

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DO - 10.3184/174751913X13639408275103

M3 - 文章

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SN - 0308-2342

VL - 37

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EP - 247

JO - Journal of Chemical Research

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φ-Conjugated molecules based on truxene cores and pyrene substitution:Synthesis and properties

Abstract

Keywords

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