Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Wen Guan; Chao Xu; Yao Chen; Yanli Mao; Zhongxian Song; Binrong Li; Yongsheng Yan; Yunlei Zhang

doi:10.1039/d6cc02599d

Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Wen Guan
, Chao Xu
, Yao Chen
, Yanli Mao
, Zhongxian Song
, Binrong Li
, Yongsheng Yan
, Yunlei Zhang

Jiangsu University
Henan University of Urban Construction
Suzhou University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9% FDCA yield with 92.9% faradaic efficiency.

源语言	英语
页（从-至）	12352-12356
页数	5
期刊	Chemical Communications
卷	62
期	49
DOI	https://doi.org/10.1039/d6cc02599d
出版状态	已出版 - 25 6月 2026
已对外发布	是

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title = "Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid",

abstract = "A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9\% FDCA yield with 92.9\% faradaic efficiency.",

author = "Wen Guan and Chao Xu and Yao Chen and Yanli Mao and Zhongxian Song and Binrong Li and Yongsheng Yan and Yunlei Zhang",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry, 2026.",

year = "2026",

month = jun,

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doi = "10.1039/d6cc02599d",

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TY - JOUR

T1 - Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

AU - Guan, Wen

AU - Xu, Chao

AU - Chen, Yao

AU - Mao, Yanli

AU - Song, Zhongxian

AU - Li, Binrong

AU - Yan, Yongsheng

AU - Zhang, Yunlei

PY - 2026/6/25

Y1 - 2026/6/25

N2 - A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9% FDCA yield with 92.9% faradaic efficiency.

AB - A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9% FDCA yield with 92.9% faradaic efficiency.

UR - https://www.scopus.com/pages/publications/105041016665

U2 - 10.1039/d6cc02599d

DO - 10.1039/d6cc02599d

M3 - 文章

AN - SCOPUS:105041016665

SN - 1359-7345

VL - 62

SP - 12352

EP - 12356

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

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