TY - JOUR
T1 - Synthesis of poly (methyl methacrylate)-b-polystyrene with high molecular weight by DPE seeded emulsion polymerization and its application in proton exchange membrane
AU - Wang, Wenwen
AU - Zhang, Hepeng
AU - Geng, Wangchang
AU - Gu, Junwei
AU - Zhou, Yanyang
AU - Zhang, Junping
AU - Zhang, Qiuyu
PY - 2013/9/15
Y1 - 2013/9/15
N2 - In this article, we present poly (methyl methacrylate)-b-polystyrene (PMMA-b-PS) with different block ratios and high molecular weight, which was synthesized by environmentally friendly seeded emulsion polymerization with 1,1-diphenylethylene (DPE) as a chain transfer agent. Polymerization kinetics in the first and second stage was investigated. Stable latex and homogeneous latex particles were obtained with the characterization of laser light scattering (LLS) and transmission electron microscopy (TEM). SEC and 1H NMR revealed the successful preparation of block copolymers with high molecular weight and two different block ratios. The morphology of microphase separation of block copolymer thin films was investigated by AFM, and long-range order lamellar morphology was observed after vapor-annealing. The block copolymer with block ratio of almost 1:1 and higher molecular weight than that of previous PMMA-b-PS was sulfonated with acetyl sulfate, and the sulfonation was confirmed by FTIR, 1H NMR, and TGA. Then, the sulfonated PMMA-b-PS was casted as membranes. The electrochemical impedance spectroscopy displayed that membranes possessed favorable proton conductivity and fine dimensional stability, and they could be candidates as proton exchange membranes.
AB - In this article, we present poly (methyl methacrylate)-b-polystyrene (PMMA-b-PS) with different block ratios and high molecular weight, which was synthesized by environmentally friendly seeded emulsion polymerization with 1,1-diphenylethylene (DPE) as a chain transfer agent. Polymerization kinetics in the first and second stage was investigated. Stable latex and homogeneous latex particles were obtained with the characterization of laser light scattering (LLS) and transmission electron microscopy (TEM). SEC and 1H NMR revealed the successful preparation of block copolymers with high molecular weight and two different block ratios. The morphology of microphase separation of block copolymer thin films was investigated by AFM, and long-range order lamellar morphology was observed after vapor-annealing. The block copolymer with block ratio of almost 1:1 and higher molecular weight than that of previous PMMA-b-PS was sulfonated with acetyl sulfate, and the sulfonation was confirmed by FTIR, 1H NMR, and TGA. Then, the sulfonated PMMA-b-PS was casted as membranes. The electrochemical impedance spectroscopy displayed that membranes possessed favorable proton conductivity and fine dimensional stability, and they could be candidates as proton exchange membranes.
KW - 1,1-Diphenylethylene
KW - Block copolymer
KW - Proton exchange membrane
KW - Seeded emulsion polymerization
UR - https://www.scopus.com/pages/publications/84880143886
U2 - 10.1016/j.jcis.2013.05.049
DO - 10.1016/j.jcis.2013.05.049
M3 - 文章
AN - SCOPUS:84880143886
SN - 0021-9797
VL - 406
SP - 154
EP - 164
JO - Journal of Colloid and Interface Science
JF - Journal of Colloid and Interface Science
ER -