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Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films

  • Guiqin Yu
  • , Shiqiang Yan
  • , Feng Zhou
  • , Xuqing Liu
  • , Weimin Liu
  • , Yongmin Liang
  • Lanzhou University
  • CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件文章同行评审

103 引用 (Scopus)

摘要

A new series of novel dicationic symmetrical and asymmetrical ionic liquids (ILs) consisting of tributylalkyl phosphonium and alkylimidazolium were synthesized. Their tribological properties in the form of spin-coated ultra-thin films sliding against AISI-52100 steel ball were studied in a ball-on-plate configuration on a Universal Micro-tribometer-2MT tester, using perfluoropolyether (PFPE) and normal ILs as comparisons. The best result is obtained for asymmetrical 1-(1-tributylphosphine-yl-hexyl)-3-methylimidazolium dihexafluorophosphate, which has very high decomposition temperature-about 450 °C and good tribological properties.

源语言英语
页(从-至)197-205
页数9
期刊Tribology Letters
25
3
DOI
出版状态已出版 - 3月 2007
已对外发布

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