Synthesis, characterization and thermal decomposition mechanism of tris-acetylacetonate iridium complex

Xin Yan; Qiuyu Zhang

doi:10.3969/j.issn.0258-7076.2010.04.021

Synthesis, characterization and thermal decomposition mechanism of tris-acetylacetonate iridium complex

Xin Yan
, Qiuyu Zhang

化学与化工学院

Chang'an University

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The Ir(acac)₃ complex was prepared by the reaction of H₂IrCl₆ and 2, 4-pentanedione, and purified by recrystallization from benzene-hexane system. The content of carbon and hydrogen in the complex was determined by elemental analysis. The results of infrared spectroscopy showed that the peak at 1549 and 1523 cm^-1 represented the vibrational modes and stretching modes of the C-O and C-C bonds in the hexahydric ring structure. The results of ¹H-NMR spectroscopy showed that the position and quantity of hydrogen chemical shift were consistent with structural formula of Ir(acac)₃ complex. And a possible thermal decomposition mechanism was studied by mass spectroscopic analysis method.

源语言	英语
页（从-至）	585-589
页数	5
期刊	Xiyou Jinshu/Chinese Journal of Rare Metals
卷	34
期	4
DOI	https://doi.org/10.3969/j.issn.0258-7076.2010.04.021
出版状态	已出版 - 7月 2010

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title = "Synthesis, characterization and thermal decomposition mechanism of tris-acetylacetonate iridium complex",

abstract = "The Ir(acac)3 complex was prepared by the reaction of H2IrCl6 and 2, 4-pentanedione, and purified by recrystallization from benzene-hexane system. The content of carbon and hydrogen in the complex was determined by elemental analysis. The results of infrared spectroscopy showed that the peak at 1549 and 1523 cm-1 represented the vibrational modes and stretching modes of the C-O and C-C bonds in the hexahydric ring structure. The results of 1H-NMR spectroscopy showed that the position and quantity of hydrogen chemical shift were consistent with structural formula of Ir(acac)3 complex. And a possible thermal decomposition mechanism was studied by mass spectroscopic analysis method.",

keywords = "2, 4-pentanedione, Iridium, Synthesis, Thermal decomposition mechanism",

author = "Xin Yan and Qiuyu Zhang",

year = "2010",

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doi = "10.3969/j.issn.0258-7076.2010.04.021",

language = "英语",

volume = "34",

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journal = "Xiyou Jinshu/Chinese Journal of Rare Metals",

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TY - JOUR

T1 - Synthesis, characterization and thermal decomposition mechanism of tris-acetylacetonate iridium complex

AU - Yan, Xin

AU - Zhang, Qiuyu

PY - 2010/7

Y1 - 2010/7

N2 - The Ir(acac)3 complex was prepared by the reaction of H2IrCl6 and 2, 4-pentanedione, and purified by recrystallization from benzene-hexane system. The content of carbon and hydrogen in the complex was determined by elemental analysis. The results of infrared spectroscopy showed that the peak at 1549 and 1523 cm-1 represented the vibrational modes and stretching modes of the C-O and C-C bonds in the hexahydric ring structure. The results of 1H-NMR spectroscopy showed that the position and quantity of hydrogen chemical shift were consistent with structural formula of Ir(acac)3 complex. And a possible thermal decomposition mechanism was studied by mass spectroscopic analysis method.

AB - The Ir(acac)3 complex was prepared by the reaction of H2IrCl6 and 2, 4-pentanedione, and purified by recrystallization from benzene-hexane system. The content of carbon and hydrogen in the complex was determined by elemental analysis. The results of infrared spectroscopy showed that the peak at 1549 and 1523 cm-1 represented the vibrational modes and stretching modes of the C-O and C-C bonds in the hexahydric ring structure. The results of 1H-NMR spectroscopy showed that the position and quantity of hydrogen chemical shift were consistent with structural formula of Ir(acac)3 complex. And a possible thermal decomposition mechanism was studied by mass spectroscopic analysis method.

KW - 2, 4-pentanedione

KW - Iridium

KW - Synthesis

KW - Thermal decomposition mechanism

UR - https://www.scopus.com/pages/publications/77956109955

U2 - 10.3969/j.issn.0258-7076.2010.04.021

DO - 10.3969/j.issn.0258-7076.2010.04.021

M3 - 文章

AN - SCOPUS:77956109955

SN - 0258-7076

VL - 34

SP - 585

EP - 589

JO - Xiyou Jinshu/Chinese Journal of Rare Metals

JF - Xiyou Jinshu/Chinese Journal of Rare Metals

IS - 4

ER -

Synthesis, characterization and thermal decomposition mechanism of tris-acetylacetonate iridium complex

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