Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

Zhenhuan Pan; Minglun Liu; Chaoyue Zheng; Deqing Gao; Wei Huang

doi:10.1002/cjoc.201700024

Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

Zhenhuan Pan
, Minglun Liu
, Chaoyue Zheng
, Deqing Gao
, Wei Huang

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

25 引用（Scopus）

摘要

The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Pt_n(H₂C=CHSiMe₂OSiMe₂CH=CH₂)_m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.

源语言	英语
页（从-至）	1227-1230
页数	4
期刊	Chinese Journal of Chemistry
卷	35
期	8
DOI	https://doi.org/10.1002/cjoc.201700024
出版状态	已出版 - 1 8月 2017
已对外发布	是

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title = "Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane",

abstract = "The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.",

keywords = "Karstedt's catalyst, aminated alkenes, hydrosilylation, selectivity",

author = "Zhenhuan Pan and Minglun Liu and Chaoyue Zheng and Deqing Gao and Wei Huang",

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AU - Pan, Zhenhuan

AU - Liu, Minglun

AU - Zheng, Chaoyue

AU - Gao, Deqing

AU - Huang, Wei

PY - 2017/8/1

Y1 - 2017/8/1

N2 - The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.

AB - The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.

KW - Karstedt's catalyst

KW - aminated alkenes

KW - hydrosilylation

KW - selectivity

UR - https://www.scopus.com/pages/publications/85020121870

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DO - 10.1002/cjoc.201700024

M3 - 文章

AN - SCOPUS:85020121870

SN - 1001-604X

VL - 35

SP - 1227

EP - 1230

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 8

ER -

Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane

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