Selective coding dielectric genes based on proton tailoring to improve microwave absorption of MOFs

Regulating dielectric genes of hollow metal-organic frameworks is a milestone project for microwave absorption (MA). However, there is still a bottleneck in deciphering the contribution of various dielectric genes, making it hard to expand the MA potential from selective encoding gene sequences. Herein, a custom-made proton tailoring strategy is used to build a controllable cavity, and meticulously designed thermodynamic regulation promotes the rearrangement of carbon atoms from disorder to order, thus enhancing the characteristics of charge transfer. Meanwhile, the defect-configuration transformation from heteroatom to vacancy and geometric configuration of hollow structure increase the polarization-related dielectric genes. Therefore, MA performance is enhanced towards broadband absorption (6.6 ​GHz, 1.78 ​mm) and high-efficiency loss (−62.5 ​dB), making samples suitable for complex open electromagnetic environments. This work realizes the tradeoff between dielectric gene sequences and provides a profound insight into the functions and sources of various microwave loss mechanisms.