Selection strategy of curing depth for vat photopolymerization 3D printing of Al₂O₃ ceramics

Vat photopolymerization (VPP) 3D printing technology allows the fabrication of complex ceramic structure components through the layer-by-layer stacking strategy. The curing depth is a crucial parameter for the stacking process, as it directly impacts the printing quality. Furthermore, this parameter exerts a profound effect on the final quality of the printed part. However, there is currently a lack of comprehensive research on how the curing depth affects VPP ceramic 3D printing. This study aims to thoroughly evaluate the impact of curing depth parameters on critical aspects of the 3D printing process, including the forming accuracy, surface quality, monomer conversion, resin pyrolysis, interlayer defects, and mechanical properties. The results of our investigation clearly demonstrate the significant influence of curing depth on the precision and performance of VPP 3D printed ceramic parts. Ceramic samples produced with higher curing depth exhibited superior surface quality (Ra<1.6 μm) but lower forming accuracy. Increasing the curing depth improved interlayer adhesion but excessive depth led to a decreased monomer conversion content from 5.2 % to 2.0 % and an internal stress in the green body. Moreover, increasing the curing depth intensified the pyrolysis process and increased the propensity for cracks forming, as confirmed by simultaneous thermal analysis and microstructure observations. The flexural strength of the sintered samples reached its maximum value of 630 MPa at three times the printing layer thickness. This study provides valuable insights for selecting appropriate curing depth parameters in VPP ceramic 3D printing.