Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

Zhijie Chen; Penghao Li; Xuan Zhang; Peng Li; Megan C. Wasson; Timur Islamoglu; J. Fraser Stoddart; Omar K. Farha

doi:10.1021/jacs.8b13710

Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

Zhijie Chen
, Penghao Li
, Xuan Zhang
, Peng Li
, Megan C. Wasson
, Timur Islamoglu
, J. Fraser Stoddart
, Omar K. Farha

Northwestern University
Fudan University
Tianjin University
University of New South Wales

科研成果: 期刊稿件 › 文章 › 同行评审

219 引用（Scopus）

摘要

Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe ³⁺ , Cr ³⁺ , and Sc ³⁺ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

源语言	英语
页（从-至）	2900-2905
页数	6
期刊	Journal of the American Chemical Society
卷	141
期	7
DOI	https://doi.org/10.1021/jacs.8b13710
出版状态	已出版 - 20 2月 2019
已对外发布	是

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title = "Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption",

abstract = " Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.",

author = "Zhijie Chen and Penghao Li and Xuan Zhang and Peng Li and Wasson, \{Megan C.\} and Timur Islamoglu and Stoddart, \{J. Fraser\} and Farha, \{Omar K.\}",

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T1 - Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

AU - Chen, Zhijie

AU - Li, Penghao

AU - Zhang, Xuan

AU - Li, Peng

AU - Wasson, Megan C.

AU - Islamoglu, Timur

AU - Stoddart, J. Fraser

AU - Farha, Omar K.

PY - 2019/2/20

Y1 - 2019/2/20

N2 - Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

AB - Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

UR - https://www.scopus.com/pages/publications/85061537747

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Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

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