摘要
In the title compound, [Cd(C 10H 6NO 2) 2] n , the Cd II atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl-ate (L -) ligands, leading to a distorted trigonal-bipyramidal geometry. The L - ligands link the Cd II atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π-π inter-actions, with centroid-centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π-π inter-action between pyridine rings [centroid-centroid distance = 3.527 (2) Å] leads to a three-dimensional supra-molecular architecture.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | m163 |
| 期刊 | Acta Crystallographica Section E: Structure Reports Online |
| 卷 | 68 |
| 期 | 2 |
| DOI | |
| 出版状态 | 已出版 - 2月 2012 |
| 已对外发布 | 是 |
学术指纹
探究 'Poly[(μ 2-quinoline-3-carboxylato-κ 2 N:O)(μ 2-quinoline-3-carboxylato-κ 3N:O,O′) cadmium]' 的科研主题。它们共同构成独一无二的学术指纹。引用此
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