Ni-Mo Nanocatalysts on N-Doped Graphite Nanotubes for Highly Efficient Electrochemical Hydrogen Evolution in Acid

Teng Wang; Yanru Guo; Zhenxing Zhou; Xinghua Chang; Jie Zheng; Xingguo Li

doi:10.1021/acsnano.6b06259

Ni-Mo Nanocatalysts on N-Doped Graphite Nanotubes for Highly Efficient Electrochemical Hydrogen Evolution in Acid

Teng Wang
, Yanru Guo
, Zhenxing Zhou
, Xinghua Chang
, Jie Zheng
, Xingguo Li

Peking University

科研成果: 期刊稿件 › 文章 › 同行评审

134 引用（Scopus）

摘要

Developing noble-metal-free catalysts for electrochemical hydrogen evolution reactions (HER) with superior stability in acid is of critical importance for large-scale, low-cost hydrogen production from water electrolysis. Herein, we report a highly efficient and stable noble-metal-free HER catalyst, which is composed of Ni and Mo₂C nanocrystals supported on N-doped graphite nanotubes. This catalyst shows very low overpotential (65 mV in 0.5 M H₂SO₄ at a current density of 10 mA cm^-2 with a Tafel plot of 67 mV/dec) and good stability for HER in acidic electrolyte, which is a promising noble-metal-free HER catalyst.

源语言	英语
页（从-至）	10397-10403
页数	7
期刊	ACS Nano
卷	10
期	11
DOI	https://doi.org/10.1021/acsnano.6b06259
出版状态	已出版 - 22 11月 2016
已对外发布	是

联合国可持续发展目标

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可持续发展目标 7 经济适用的清洁能源

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10.1021/acsnano.6b06259

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title = "Ni-Mo Nanocatalysts on N-Doped Graphite Nanotubes for Highly Efficient Electrochemical Hydrogen Evolution in Acid",

abstract = "Developing noble-metal-free catalysts for electrochemical hydrogen evolution reactions (HER) with superior stability in acid is of critical importance for large-scale, low-cost hydrogen production from water electrolysis. Herein, we report a highly efficient and stable noble-metal-free HER catalyst, which is composed of Ni and Mo2C nanocrystals supported on N-doped graphite nanotubes. This catalyst shows very low overpotential (65 mV in 0.5 M H2SO4 at a current density of 10 mA cm-2 with a Tafel plot of 67 mV/dec) and good stability for HER in acidic electrolyte, which is a promising noble-metal-free HER catalyst.",

keywords = "graphite nanotube, hydrogen evolution reaction, Ni-Mo catalyst, nitrogen doping, water splitting",

author = "Teng Wang and Yanru Guo and Zhenxing Zhou and Xinghua Chang and Jie Zheng and Xingguo Li",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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doi = "10.1021/acsnano.6b06259",

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TY - JOUR

T1 - Ni-Mo Nanocatalysts on N-Doped Graphite Nanotubes for Highly Efficient Electrochemical Hydrogen Evolution in Acid

AU - Wang, Teng

AU - Guo, Yanru

AU - Zhou, Zhenxing

AU - Chang, Xinghua

AU - Zheng, Jie

AU - Li, Xingguo

PY - 2016/11/22

Y1 - 2016/11/22

N2 - Developing noble-metal-free catalysts for electrochemical hydrogen evolution reactions (HER) with superior stability in acid is of critical importance for large-scale, low-cost hydrogen production from water electrolysis. Herein, we report a highly efficient and stable noble-metal-free HER catalyst, which is composed of Ni and Mo2C nanocrystals supported on N-doped graphite nanotubes. This catalyst shows very low overpotential (65 mV in 0.5 M H2SO4 at a current density of 10 mA cm-2 with a Tafel plot of 67 mV/dec) and good stability for HER in acidic electrolyte, which is a promising noble-metal-free HER catalyst.

AB - Developing noble-metal-free catalysts for electrochemical hydrogen evolution reactions (HER) with superior stability in acid is of critical importance for large-scale, low-cost hydrogen production from water electrolysis. Herein, we report a highly efficient and stable noble-metal-free HER catalyst, which is composed of Ni and Mo2C nanocrystals supported on N-doped graphite nanotubes. This catalyst shows very low overpotential (65 mV in 0.5 M H2SO4 at a current density of 10 mA cm-2 with a Tafel plot of 67 mV/dec) and good stability for HER in acidic electrolyte, which is a promising noble-metal-free HER catalyst.

KW - graphite nanotube

KW - hydrogen evolution reaction

KW - Ni-Mo catalyst

KW - nitrogen doping

KW - water splitting

UR - https://www.scopus.com/pages/publications/84997120359

U2 - 10.1021/acsnano.6b06259

DO - 10.1021/acsnano.6b06259

M3 - 文章

AN - SCOPUS:84997120359

SN - 1936-0851

VL - 10

SP - 10397

EP - 10403

JO - ACS Nano

JF - ACS Nano

IS - 11

ER -

Ni-Mo Nanocatalysts on N-Doped Graphite Nanotubes for Highly Efficient Electrochemical Hydrogen Evolution in Acid

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