New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

Bing Liu; Cao Fang; Zhi Bing Dong; Jin Shan Li

doi:10.2174/157017807780737327

New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

Bing Liu
, Cao Fang
, Zhi Bing Dong
, Jin Shan Li

Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).

源语言	英语
页（从-至）	172-174
页数	3
期刊	Letters in Organic Chemistry
卷	4
期	3
DOI	https://doi.org/10.2174/157017807780737327
出版状态	已出版 - 4月 2007
已对外发布	是

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title = "New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide",

abstract = "We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67\% ee).",

keywords = "Asymmetric addition, BINOL, Diethylzinc, Schiff base, Titanium",

author = "Bing Liu and Cao Fang and Dong, \{Zhi Bing\} and Li, \{Jin Shan\}",

year = "2007",

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doi = "10.2174/157017807780737327",

language = "英语",

volume = "4",

pages = "172--174",

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T1 - New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

AU - Liu, Bing

AU - Fang, Cao

AU - Dong, Zhi Bing

AU - Li, Jin Shan

PY - 2007/4

Y1 - 2007/4

N2 - We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).

AB - We have developed three new chiral 3-substituted BINOL Schiff base ligands for the asymmetric diethylzine addition to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active second alcohols in high yield and moderate enantioselectivity (up to 67% ee).

KW - Asymmetric addition

KW - BINOL

KW - Diethylzinc

KW - Schiff base

KW - Titanium

UR - https://www.scopus.com/pages/publications/35649011457

U2 - 10.2174/157017807780737327

DO - 10.2174/157017807780737327

M3 - 文章

AN - SCOPUS:35649011457

SN - 1570-1786

VL - 4

SP - 172

EP - 174

JO - Letters in Organic Chemistry

JF - Letters in Organic Chemistry

IS - 3

ER -

New BINOL Schiff base as a tridentate ligand for catalytic asymmetric addition of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide

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