Modulating surface charge and d-band center via Mo doping: boosting 5-hydroxymethylfurfural electrooxidation over Cu(OH)2 catalysts

Wen Guan; Mengyang Xu; Wen Zhang; Yao Chen; Yanli Mao; Zhongxian Song; Yongsheng Yan; Yunlei Zhang

doi:10.1039/d6cc03774g

Modulating surface charge and d-band center via Mo doping: boosting 5-hydroxymethylfurfural electrooxidation over Cu(OH)₂ catalysts

Wen Guan
, Mengyang Xu
, Wen Zhang
, Yao Chen
, Yanli Mao
, Zhongxian Song
, Yongsheng Yan
, Yunlei Zhang

Jiangsu University
Henan University of Urban Construction

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

To address poor HMF adsorption and weak OH⁻ activation of Cu(OH)₂, Mo-doped Cu(OH)₂ nanowire arrays were synthesized via chemical etching. Optimal Mo doping minimizes the surface negative charge, enhances HMF adsorption, and achieves 99.9% conversion, 99.9% FDCA yield, and nearly 100% FE at 1.66 V vs. RHE within 2 hours.

源语言	英语
期刊	Chemical Communications
DOI	https://doi.org/10.1039/d6cc03774g
出版状态	已接受/待刊 - 2026
已对外发布	是

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10.1039/d6cc03774g

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@article{89eaed331f0148d9accd28bbcf7bf510,

title = "Modulating surface charge and d-band center via Mo doping: boosting 5-hydroxymethylfurfural electrooxidation over Cu(OH)2 catalysts",

abstract = "To address poor HMF adsorption and weak OH− activation of Cu(OH)2, Mo-doped Cu(OH)2 nanowire arrays were synthesized via chemical etching. Optimal Mo doping minimizes the surface negative charge, enhances HMF adsorption, and achieves 99.9\% conversion, 99.9\% FDCA yield, and nearly 100\% FE at 1.66 V vs. RHE within 2 hours.",

author = "Wen Guan and Mengyang Xu and Wen Zhang and Yao Chen and Yanli Mao and Zhongxian Song and Yongsheng Yan and Yunlei Zhang",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry, 2026.",

year = "2026",

doi = "10.1039/d6cc03774g",

language = "英语",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Modulating surface charge and d-band center via Mo doping

T2 - boosting 5-hydroxymethylfurfural electrooxidation over Cu(OH)2 catalysts

AU - Guan, Wen

AU - Xu, Mengyang

AU - Zhang, Wen

AU - Chen, Yao

AU - Mao, Yanli

AU - Song, Zhongxian

AU - Yan, Yongsheng

AU - Zhang, Yunlei

PY - 2026

Y1 - 2026

N2 - To address poor HMF adsorption and weak OH− activation of Cu(OH)2, Mo-doped Cu(OH)2 nanowire arrays were synthesized via chemical etching. Optimal Mo doping minimizes the surface negative charge, enhances HMF adsorption, and achieves 99.9% conversion, 99.9% FDCA yield, and nearly 100% FE at 1.66 V vs. RHE within 2 hours.

AB - To address poor HMF adsorption and weak OH− activation of Cu(OH)2, Mo-doped Cu(OH)2 nanowire arrays were synthesized via chemical etching. Optimal Mo doping minimizes the surface negative charge, enhances HMF adsorption, and achieves 99.9% conversion, 99.9% FDCA yield, and nearly 100% FE at 1.66 V vs. RHE within 2 hours.

UR - https://www.scopus.com/pages/publications/105047946068

U2 - 10.1039/d6cc03774g

DO - 10.1039/d6cc03774g

M3 - 文章

C2 - 42610194

AN - SCOPUS:105047946068

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Modulating surface charge and d-band center via Mo doping: boosting 5-hydroxymethylfurfural electrooxidation over Cu(OH)2 catalysts

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Modulating surface charge and d-band center via Mo doping: boosting 5-hydroxymethylfurfural electrooxidation over Cu(OH)₂ catalysts