TY - JOUR
T1 - Metal naphthalenedicarboxylates with diverse network architectures
T2 - Synthesis, crystal structures and properties
AU - Jiang, Xiu Juan
AU - Guo, Jian Hua
AU - Du, Miao
AU - Li, Jin Shan
PY - 2009/11/16
Y1 - 2009/11/16
N2 - Reactions of 1,4-naphthalenedicarboxylic acid (1,4-H2nda) and a bent dipyridyl co-ligand 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole (4bpt) with CoII, ZnII, or CdII acetate afford four coordination polymers, [Co(1,4-nda)(4bpt)(H2O)]n (1), {[Co(1,4-nda)2(4bpt)(H2O)2][Co(4bpt)(H2O)4](H2O)1.5}n (2), {[Zn(1,4-nda)2(4bpt)(H2O)2][Zn(4bpt)(H2O)4](H2O)1.5}n (3), and {[Cd2(1,4-nda)2(4bpt)2(H2O)2](DMF)1.5(H2O)3}n (4). In the structure of the CoII complex 1, the polycatenation of inclined 2-D (4,4) coordination layers leads to the formation of a 3-D supramolecular framework, whereas two types of 1-D polymeric chains are observed in another CoII coordination species 2, which are interconnected via H-bonding to result in an unusual 3-D host-guest lattice. Notably, complexes 1 and 2 have been prepared under similar hydrothermal conditions and their structural discrepancy can only be ascribed to a subtle change of basicity for the reaction solution. The ZnII complex 3 is isostructural to 2, and the CdII complex 4 displays a 2-fold parallel interpenetrating array of undulating (4,4) coordination layers. By using the conventional solvent evaporation method, two PbII naphthalenedicarboxylates [Pb(1,4-nda)(DMF)]n (5) and {[Pb2(2,6-nda)2(DMF)2](DMF)}n (6) have also been prepared (2,6-nda = 2,6-naphthalenedicarboxylate). Complex 5 has a unique 5-connected 3-D coordination architecture, whereas 6 represents a 3-fold interpenetrating framework of 4-connected diamond topology. Their structural difference suggests the significant isomeric effect of the naphthalenedicarboxylate tectons on structural assemblies. Thermal stability of these crystalline materials has been investigated by thermogravimetric and differential thermal analysis (TG-DTA) technique and solid-state luminescent properties of the ZnII, CdII, and PbII complexes have also been explored.
AB - Reactions of 1,4-naphthalenedicarboxylic acid (1,4-H2nda) and a bent dipyridyl co-ligand 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole (4bpt) with CoII, ZnII, or CdII acetate afford four coordination polymers, [Co(1,4-nda)(4bpt)(H2O)]n (1), {[Co(1,4-nda)2(4bpt)(H2O)2][Co(4bpt)(H2O)4](H2O)1.5}n (2), {[Zn(1,4-nda)2(4bpt)(H2O)2][Zn(4bpt)(H2O)4](H2O)1.5}n (3), and {[Cd2(1,4-nda)2(4bpt)2(H2O)2](DMF)1.5(H2O)3}n (4). In the structure of the CoII complex 1, the polycatenation of inclined 2-D (4,4) coordination layers leads to the formation of a 3-D supramolecular framework, whereas two types of 1-D polymeric chains are observed in another CoII coordination species 2, which are interconnected via H-bonding to result in an unusual 3-D host-guest lattice. Notably, complexes 1 and 2 have been prepared under similar hydrothermal conditions and their structural discrepancy can only be ascribed to a subtle change of basicity for the reaction solution. The ZnII complex 3 is isostructural to 2, and the CdII complex 4 displays a 2-fold parallel interpenetrating array of undulating (4,4) coordination layers. By using the conventional solvent evaporation method, two PbII naphthalenedicarboxylates [Pb(1,4-nda)(DMF)]n (5) and {[Pb2(2,6-nda)2(DMF)2](DMF)}n (6) have also been prepared (2,6-nda = 2,6-naphthalenedicarboxylate). Complex 5 has a unique 5-connected 3-D coordination architecture, whereas 6 represents a 3-fold interpenetrating framework of 4-connected diamond topology. Their structural difference suggests the significant isomeric effect of the naphthalenedicarboxylate tectons on structural assemblies. Thermal stability of these crystalline materials has been investigated by thermogravimetric and differential thermal analysis (TG-DTA) technique and solid-state luminescent properties of the ZnII, CdII, and PbII complexes have also been explored.
KW - Fluorescence
KW - Metal naphthalenedicarboxylate
KW - Network architecture
KW - Structural regulation
KW - Thermal stability
UR - https://www.scopus.com/pages/publications/70350505910
U2 - 10.1016/j.poly.2009.08.022
DO - 10.1016/j.poly.2009.08.022
M3 - 文章
AN - SCOPUS:70350505910
SN - 0277-5387
VL - 28
SP - 3759
EP - 3768
JO - Polyhedron
JF - Polyhedron
IS - 17
ER -